UNSPECIFIED (2003) Characterisation of the interaction of glycine with Cu(100) and Cu(111). Surface Science, 531 (3). pp. 304-318. ISSN 0039-6028

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Abstract

Reflection-absorption infrared spectroscopy (RAIRS) has been used to characterise the interaction of standard and fully deuterated glycine with Cu(1 0 0) and Cu(1 1 1). RAIRS shows clearly that the surface interaction leads to formation of the adsorbed deprotonated glycinate (NH2CH2COO-) species, with some evidence for changes in orientation with coverage previously seen on Cu(1 1 0). Qualitative low energy electron diffraction observations were also conducted to characterise the long-range ordering, although effects of electron-beam-induced radiation damage limited the information obtained. Nevertheless, the results do suggest some subtle isotopic-mass-related structural variations. The results are discussed in the context of previously published scanning tunnelling microscopy and photoelectron diffraction measurements. (C) 2003 Elsevier Science B.V. All rights reserved.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry Q Science > QC Physics
Journal or Publication Title:	Surface Science
Publisher:	ELSEVIER SCIENCE BV
ISSN:	0039-6028
Date:	1 June 2003
Volume:	531
Number:	3
Number of Pages:	15
Page Range:	pp. 304-318
Publication Status:	Published
URI:	http://wrap.warwick.ac.uk/id/eprint/9674

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