Synthesis, structure, and stability in acid of copper(II) and zinc(II) complexes of cross-bridged tetraazamacrocycles
UNSPECIFIED. (2003) Synthesis, structure, and stability in acid of copper(II) and zinc(II) complexes of cross-bridged tetraazamacrocycles. Inorganica Chimica Acta, 348 . pp. 33-40. ISSN 0020-1693Full text not available from this repository.
Official URL: http://dx.doi.org/10.1016/S0020-1693(03)00036-7
New copper(II) and zinc(II) complexes of cross-bridged tetraazamacrocyclic ligands derived from 1,4,8,11-tetraazacyclotetradecane (cyclam), 1,4,7,10-tetraazacyclotridecane(aneN4), and 1,4,7,10-tetraazacyclododecane (cyclen) have been synthesized. The X-ray crystal structures of the two cyclen-derived complexes have been determined and show both metal ions to be in distorted octahedral environments with the ligand in a cis-folded conformation. The bridged-ligand complexes are remarkably stable kinetically under harsh acidic conditions, as seen from their dissociation reactions. The electrochemical and spectroscopic properties of the Cu2+ complexes have also been investigated. (C) 2003 Elsevier Science B.V. All rights reserved.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||Inorganica Chimica Acta|
|Publisher:||ELSEVIER SCIENCE SA|
|Official Date:||15 May 2003|
|Number of Pages:||8|
|Page Range:||pp. 33-40|
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