The Library
Synthesis, structure, and stability in acid of copper(II) and zinc(II) complexes of cross-bridged tetraazamacrocycles
Tools
UNSPECIFIED (2003) Synthesis, structure, and stability in acid of copper(II) and zinc(II) complexes of cross-bridged tetraazamacrocycles. Inorganica Chimica Acta, 348 . pp. 33-40. doi:10.1016/S0020-1693(03)00036-7 ISSN 0020-1693.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Official URL: http://dx.doi.org/10.1016/S0020-1693(03)00036-7
Abstract
New copper(II) and zinc(II) complexes of cross-bridged tetraazamacrocyclic ligands derived from 1,4,8,11-tetraazacyclotetradecane (cyclam), 1,4,7,10-tetraazacyclotridecane([13]aneN4), and 1,4,7,10-tetraazacyclododecane (cyclen) have been synthesized. The X-ray crystal structures of the two cyclen-derived complexes have been determined and show both metal ions to be in distorted octahedral environments with the ligand in a cis-folded conformation. The bridged-ligand complexes are remarkably stable kinetically under harsh acidic conditions, as seen from their dissociation reactions. The electrochemical and spectroscopic properties of the Cu2+ complexes have also been investigated. (C) 2003 Elsevier Science B.V. All rights reserved.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | Inorganica Chimica Acta | ||||
Publisher: | ELSEVIER SCIENCE SA | ||||
ISSN: | 0020-1693 | ||||
Official Date: | 15 May 2003 | ||||
Dates: |
|
||||
Volume: | 348 | ||||
Number of Pages: | 8 | ||||
Page Range: | pp. 33-40 | ||||
DOI: | 10.1016/S0020-1693(03)00036-7 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |