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Synthesis of enantiomerically-pure and racemic benzyl-tethered Ru (II)/TsDPEN complexes by direct arene substitution : further complexes and application
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Wills, Martin, Jolley, Katherine E., Gosiewska, Silvia, Clarkson, Guy J., Fang, Zhijia, Hall, Thomas Howard, Treloar, Ben and Knighton, Richard C. (2018) Synthesis of enantiomerically-pure and racemic benzyl-tethered Ru (II)/TsDPEN complexes by direct arene substitution : further complexes and application. Organometallics, 37 (1). pp. 48-64. doi:10.1021/acs.organomet.7b00731 ISSN 0276-7333.
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Official URL: http://doi.org/10.1021/acs.organomet.7b00731
Abstract
The use of a direct arene-exchange method for the synthesis of benzyl-tethered arene/Ru/TsDPEN complexes for use in asymmetric transfer hydrogenation is reported. A series of complexes tethered through a three-carbon linear chain was also prepared. The arene-exchange approach significantly simplifies the synthetic approach to this class of catalyst and permits the ready formation of modified analogues. The approach also provides a route to racemic catalysts for use in general reductions with either hydrogen or transfer hydrogenation
Item Type: | Journal Article | |||||||||||||||||||||||||||
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Subjects: | Q Science > QD Chemistry | |||||||||||||||||||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | |||||||||||||||||||||||||||
Library of Congress Subject Headings (LCSH): | Aromatic compounds -- Synthesis, Hydrogenation | |||||||||||||||||||||||||||
Journal or Publication Title: | Organometallics | |||||||||||||||||||||||||||
Publisher: | American Chemical Society | |||||||||||||||||||||||||||
ISSN: | 0276-7333 | |||||||||||||||||||||||||||
Official Date: | 8 January 2018 | |||||||||||||||||||||||||||
Dates: |
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Volume: | 37 | |||||||||||||||||||||||||||
Number: | 1 | |||||||||||||||||||||||||||
Page Range: | pp. 48-64 | |||||||||||||||||||||||||||
DOI: | 10.1021/acs.organomet.7b00731 | |||||||||||||||||||||||||||
Status: | Peer Reviewed | |||||||||||||||||||||||||||
Publication Status: | Published | |||||||||||||||||||||||||||
Access rights to Published version: | Restricted or Subscription Access | |||||||||||||||||||||||||||
Copyright Holders: | American Chemical Society | |||||||||||||||||||||||||||
Date of first compliant deposit: | 5 January 2018 | |||||||||||||||||||||||||||
Date of first compliant Open Access: | 20 December 2018 | |||||||||||||||||||||||||||
RIOXX Funder/Project Grant: |
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