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Alternative monolithic/composite carbons for adsorption generators and simulation for optimal performance

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Rivero Pacho, Angeles M., Critoph, Robert E. and Metcalf, Steven J. (2017) Alternative monolithic/composite carbons for adsorption generators and simulation for optimal performance. Applied Thermal Engineering, 126 . pp. 350-357. doi:10.1016/j.applthermaleng.2017.07.177 ISSN 1359-4311.

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Official URL: http://dx.doi.org/10.1016/j.applthermaleng.2017.07...

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Abstract

This paper presents the development and thermal properties study of three types of carbon composites with enhanced thermal properties along with the optimisation of the geometry of the shell and tube generators currently used at the University of Warwick for the development of carbon-ammonia heat pumps.

The three carbon composites developed use lignin binder, silanes binder and Expanded Natural Graphite (ENG) as a way of enhancing their thermal properties in order to perform more efficiently in a refrigeration or heating system. Two techniques were used in order to obtain the thermal properties: Anter and HyperFlash thermal conductivity instruments.

Results show that ENG increases drastically the thermal conductivity of the samples (up to 3.4 W/(mK)) but reduces the carbon density (450 kg/m3) and increases the thermal mass of the system. Lignin binder samples show lower thermal conductivities (0.3 W/(mK)) but higher carbon densities (750 kg/m3) which increases the performance of the machine. Thermal conductivities of samples were also obtained for a wide range of working temperatures (25–200 °C).

The current development of gas fired heat pumps at Warwick uses shell and tube adsorption generators with over 1000 water tubes of 1.2 mm diameter on a 3 mm pitch. This geometry is not optimised and a dynamic simulation program has been written to determine how far from optimal the design is and also whether alternative designs offer advantages.

The results presented show that the shell and tube is close to optimal for its type but that finned tube designs might offer improvements.

Item Type: Journal Article
Subjects: T Technology > TA Engineering (General). Civil engineering (General)
Divisions: Faculty of Science, Engineering and Medicine > Engineering > Engineering
Library of Congress Subject Headings (LCSH): Carbon composites -- Thermal properties, Heat pumps -- Thermodynamics, Ammonia -- Industrial applications
Journal or Publication Title: Applied Thermal Engineering
Publisher: Pergamon
ISSN: 1359-4311
Official Date: 5 November 2017
Dates:
DateEvent
5 November 2017Published
26 July 2017Available
25 July 2017Accepted
Volume: 126
Page Range: pp. 350-357
DOI: 10.1016/j.applthermaleng.2017.07.177
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Date of first compliant deposit: 6 February 2018
Date of first compliant Open Access: 26 July 2018

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