The aryl cation - The trapping and characterisation of a hyper-reactive species
UNSPECIFIED (2003) The aryl cation - The trapping and characterisation of a hyper-reactive species. PROGRESS IN REACTION KINETICS AND MECHANISM, 28 (1). pp. 11-33. ISSN 1468-6783Full text not available from this repository.
The article traces the development of the epr and optical spectroscopic characterisation and progressive theoretical understanding of the aryl cation, starting from the initial cryogenic epr study of 2,5-dialkoxyl-4-morpholinophenyl cation, which defined unambiguously its triplet state character, through simple MO, ab initio and DFT calculations on substituted aryl cations, to picosecond laser photolysis studies in fluorinated solvents, noting especially the early and vital contribution of Martyn Symons.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||PROGRESS IN REACTION KINETICS AND MECHANISM|
|Number of Pages:||23|
|Page Range:||pp. 11-33|
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