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Lignin-containing feedstock hydrogenolysis for biofuel component production

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Shimanskaya, Elena, Stepacheva, Аntonina A., Sulman, Esther, Rebrov, Evgeny V. and Matveeva, Valentina (2018) Lignin-containing feedstock hydrogenolysis for biofuel component production. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (1). pp. 74-81. doi:10.9767/bcrec.13.1.969.74-81

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Official URL: http://dx.doi.org/10.9767/bcrec.13.1.969.74-81

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Abstract

In this paper, the commercial 5%Pd/C and 5%Pt/C catalysts and synthesized 5%Pt/MN-270 and 5%Pd/MN-270 were used in the hydrogenolysis of lignocellulosic material (softwood sawdust) to obtain liquid fuels in the form of hydrocarbons. As lignin has a very complex structure, anisole was used as a model compound. It was found that the use Pt-containing catalysts based on hypercrosslinked polystyrene in both processes of anisole and lignin-containing feedstock conversion allowed obtaining the highest yield of oxygen-free hydrocarbons (up to 96 wt. %). Besides, the polymer based catalysts showed high stability in hydrogenolysis process in comparison with the commercial carbon based catalysts.

Item Type: Journal Article
Subjects: T Technology > TP Chemical technology
Divisions: Faculty of Science > Engineering
Library of Congress Subject Headings (LCSH): Biomass energy, Hydrogenolysis, Lignin
Journal or Publication Title: Bulletin of Chemical Reaction Engineering & Catalysis
Publisher: Diponegoro University ; Masyarakat Katalis Indonesia
ISSN: 1978-2993
Official Date: 4 February 2018
Dates:
DateEvent
4 February 2018Published
22 January 2018Available
21 August 2017Accepted
Volume: 13
Number: 1
Page Range: pp. 74-81
DOI: 10.9767/bcrec.13.1.969.74-81
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Open Access
RIOXX Funder/Project Grant:
Project/Grant IDRIOXX Funder NameFunder ID
15-13-20015Russian Science Foundationhttp://dx.doi.org/10.13039/501100006769
18-08-00609 ARussian Foundation for Basic Researchhttp://dx.doi.org/10.13039/501100002261

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