UNSPECIFIED (2003) Cation coordination in oxychloride glasses. JOURNAL OF PHYSICS-CONDENSED MATTER, 15 (6). pp. 755-764. ISSN 0953-8984

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Abstract

Glasses containing mixtures of cations and anions of nominal compositions [Sb2O3](x)-[ZnCl2](1-x) where x = 0.25, 0.50, 0.75, and 1.00, have been studied by means of neutron diffraction and Raman and Mossbauer spectroscopy. There is preferential bonding within the system with the absence of Sb-Cl bonds. Antimony is found to be threefold coordinated to oxygen, and zinc fourfold coordinated. The main contributing species are of the form [Sb(OSb)(2)(OZn)] and [Zn(ClZn)(2)(OSb)(2)].

Item Type:	Journal Article
Subjects:	Q Science > QC Physics
Journal or Publication Title:	JOURNAL OF PHYSICS-CONDENSED MATTER
Publisher:	IOP PUBLISHING LTD
ISSN:	0953-8984
Date:	19 February 2003
Volume:	15
Number:	6
Number of Pages:	10
Page Range:	pp. 755-764
Publication Status:	Published
URI:	http://wrap.warwick.ac.uk/id/eprint/9894

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