Cation coordination in oxychloride glasses
UNSPECIFIED. (2003) Cation coordination in oxychloride glasses. JOURNAL OF PHYSICS-CONDENSED MATTER, 15 (6). pp. 755-764. ISSN 0953-8984Full text not available from this repository.
Glasses containing mixtures of cations and anions of nominal compositions [Sb2O3](x)-[ZnCl2](1-x) where x = 0.25, 0.50, 0.75, and 1.00, have been studied by means of neutron diffraction and Raman and Mossbauer spectroscopy. There is preferential bonding within the system with the absence of Sb-Cl bonds. Antimony is found to be threefold coordinated to oxygen, and zinc fourfold coordinated. The main contributing species are of the form [Sb(OSb)(2)(OZn)] and [Zn(ClZn)(2)(OSb)(2)].
|Item Type:||Journal Article|
|Subjects:||Q Science > QC Physics|
|Journal or Publication Title:||JOURNAL OF PHYSICS-CONDENSED MATTER|
|Publisher:||IOP PUBLISHING LTD|
|Date:||19 February 2003|
|Number of Pages:||10|
|Page Range:||pp. 755-764|
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