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Dynamic kinetic resolution-asymmetric transfer hydrogenation of 1-aryl-substituted cyclic ketones
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UNSPECIFIED (2002) Dynamic kinetic resolution-asymmetric transfer hydrogenation of 1-aryl-substituted cyclic ketones. TETRAHEDRON-ASYMMETRY, 13 (22). pp. 2485-2490. ISSN 0957-4166.
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Abstract
A range of 1-aryl-2-tetranols, and 1-phenyl-2-indanol, have been generated in high yield and enantiomeric excess from the corresponding racemic ketones, via a dynamic kinetic resolution-transfer hydrogenation process, using Ru(II)-TsDPEN in formic acid/triethylamine (5:2). This provides a potential entry to an asymmetric total synthesis of benzazepines such as Sch 39166. (C) 2002 Elsevier Science Ltd. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | TETRAHEDRON-ASYMMETRY | ||||
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
ISSN: | 0957-4166 | ||||
Official Date: | 13 November 2002 | ||||
Dates: |
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Volume: | 13 | ||||
Number: | 22 | ||||
Number of Pages: | 6 | ||||
Page Range: | pp. 2485-2490 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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