The Library
Chiral biarylamido complexes of zirconium
Tools
UNSPECIFIED (2002) Chiral biarylamido complexes of zirconium. ORGANOMETALLICS, 21 (21). pp. 4496-4504. doi:10.1021/om020471p ISSN 0276-7333.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Official URL: http://dx.doi.org/10.1021/om020471p
Abstract
The palladium-catalyzed arylation of 2,2'-diamino-6,6'-dimethylbiphenyl with (variously) bromo-3,5-di-tert-butylbenzene, 2-bromopyridine, 2-methylbromopyridine, bromomesitylene, and 2-bromo-4-methylanisole gives three C-2-symmetric and three C-1-symmetric biaryl-bridged diamino proligands H2L. The subsequent amine elimination (protonolysis) reactions of these with tetrakis(dimethylamido)zirconium yields a range of crystalline complexes [Zr(L)(NMe2)(2)]. X-ray crystallography reveals molecular structures of five examples with ligated amido, aminopridinato, and aminoanisolato units.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | ORGANOMETALLICS | ||||
Publisher: | AMER CHEMICAL SOC | ||||
ISSN: | 0276-7333 | ||||
Official Date: | 14 October 2002 | ||||
Dates: |
|
||||
Volume: | 21 | ||||
Number: | 21 | ||||
Number of Pages: | 9 | ||||
Page Range: | pp. 4496-4504 | ||||
DOI: | 10.1021/om020471p | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |