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Palladium catalyzed oxidation of monoterpenes: novel oxidation of myrcene with dioxygen
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UNSPECIFIED (2002) Palladium catalyzed oxidation of monoterpenes: novel oxidation of myrcene with dioxygen. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 185 (1-2). pp. 97-104. ISSN 1381-1169.
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Abstract
Myrcene can be efficiently and selectively oxidized by dioxygen in glacial acetic acid containing LiCl, in the presence of the PdC2-CuCl2 catalytic combination, yielding two isomers of a new functionalized monoterpene, i.e., 3-(1-acetoxy-1-methylethyl)-1-vinylcyclopentene and 4-(1-acetoxy-1-methylethyl)-1-vinylcyclopentene, as major products. These compounds have a pleasant scent with a flower or fruit tinge and could be used as components of synthetic perfumes. The activities of Pd(OAc)(2)-LiNO3, Pd(OAc)(2)-Cu(NO3)(2) and Pd(OAc)(2)-benzoquinone systems in myrcene oxidation have also been examined. (C) 2002 Elsevier Science B.V. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | ||||
Publisher: | ELSEVIER SCIENCE BV | ||||
ISSN: | 1381-1169 | ||||
Official Date: | 8 July 2002 | ||||
Dates: |
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Volume: | 185 | ||||
Number: | 1-2 | ||||
Number of Pages: | 8 | ||||
Page Range: | pp. 97-104 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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