The Library
C-13 kinetic isotope effects in the copper(I)-mediated living radical polymerization of methyl methacrylate
Tools
UNSPECIFIED (2002) C-13 kinetic isotope effects in the copper(I)-mediated living radical polymerization of methyl methacrylate. CHEMICAL COMMUNICATIONS (14). pp. 1470-1471. doi:10.1039/b203675d ISSN 1359-7345.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Official URL: http://dx.doi.org/10.1039/b203675d
Abstract
Carbon-13 kinetic isotope effects (KIEs) have been determined for free-radical and copper-mediated living radical polymerizations of methyl methacrylate at 60degreesC. While free-radical polymerization shows only one primary C-13 KIE, on the least-substituted double bond carbon (k(12)/k(13) = 1.045), two significant KIEs are observed, one on each double bond carbon, for copper-mediated polymerization (k(12)/k(13)(H2C) = 1.050, k(12)/k(13)(=C<) = 1.010), showing that copper-mediated living radical polymerization does not propagate via a simple free radical process.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | CHEMICAL COMMUNICATIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 1359-7345 | ||||
Official Date: | 2002 | ||||
Dates: |
|
||||
Number: | 14 | ||||
Number of Pages: | 2 | ||||
Page Range: | pp. 1470-1471 | ||||
DOI: | 10.1039/b203675d | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |