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Doubly cyclopalladated pyridazines: chiral liquid crystals
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UNSPECIFIED (2002) Doubly cyclopalladated pyridazines: chiral liquid crystals. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 645 (1-2). pp. 246-255. ISSN 0022-328X.
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Abstract
The mono and dicyclopalladation of new mesogenic pyridazines and subsequent reaction with beta-diketones yields some novel metallomesogens. The monometallated derivatives have a flat central core. In contrast. the dimetallated derivatives have a sterically induced twist in the molecule that renders them chiral. Smectic A phases are typically exhibited by both the derivatives with transition temperatures in the region of 100-300 degreesC. (C) 2002 Elsevier Science B.V. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF ORGANOMETALLIC CHEMISTRY | ||||
Publisher: | ELSEVIER SCIENCE SA | ||||
ISSN: | 0022-328X | ||||
Official Date: | 15 February 2002 | ||||
Dates: |
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Volume: | 645 | ||||
Number: | 1-2 | ||||
Number of Pages: | 10 | ||||
Page Range: | pp. 246-255 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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