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Back bonding without sigma-bonding: a unique pi-complex of dinitrogen with uranium
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UNSPECIFIED (2001) Back bonding without sigma-bonding: a unique pi-complex of dinitrogen with uranium. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 635 (1-2 Sp. Iss. SI). pp. 69-74. ISSN 0022-328X.
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Abstract
The synthesis, molecular structure, spectroscopic properties and bonding in a complex of dinitrogen with trivalent uranium are described. The molecule has a side-on U-N-2-U Core which is supported by U -->N-2 pi donation with no significant N-2 --> U bonding. Steric compression between the spectator triamidoamine ligands prevents the uranium atoms from approaching the N-2 ligand at the optimum distance for overlap, and thus the N-N distance is not displaced significantly from that in gaseous dinitrogen. (C) 2001 Elsevier Science BN. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF ORGANOMETALLIC CHEMISTRY | ||||
Publisher: | ELSEVIER SCIENCE SA | ||||
ISSN: | 0022-328X | ||||
Official Date: | 15 October 2001 | ||||
Dates: |
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Volume: | 635 | ||||
Number: | 1-2 Sp. Iss. SI | ||||
Number of Pages: | 6 | ||||
Page Range: | pp. 69-74 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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