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Rearrangement of unactivated N-alkyl-O-benzoyl hydroxamic acid derivatives with phosphazene bases
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UNSPECIFIED (2001) Rearrangement of unactivated N-alkyl-O-benzoyl hydroxamic acid derivatives with phosphazene bases. TETRAHEDRON LETTERS, 42 (10). pp. 2007-2009. ISSN 0040-4039.
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Abstract
The phosphazene super bases BTPP 5, P-2-'Bu 6, and P-4-'Bu 7 mediate the rearrangement of unactivated N-alkyl-O-benzoyl hydroxamic acid derivatives 8, 11a-f, 13 and 16 to give 2-benzoyloxy amides 9, 12a-f, 14 and 17. The rate of reaction was found to be dependant upon the steric nature of the N-alkyl substituent. (C) 2001 Elsevier Science Ltd. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | TETRAHEDRON LETTERS | ||||
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
ISSN: | 0040-4039 | ||||
Official Date: | 4 March 2001 | ||||
Dates: |
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Volume: | 42 | ||||
Number: | 10 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 2007-2009 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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