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Specific formation of (M-H)(-) ions from OH-group-containing molecules
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UNSPECIFIED (2001) Specific formation of (M-H)(-) ions from OH-group-containing molecules. INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 205 (1-3 Sp. Iss. SI). pp. 119-135. ISSN 1387-3806.
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Abstract
The formation of (M-H)(-) ions from OH-containing benzene derivatives, covering azobenzenes and phenols, has been investigated by resonant electron-capture mass spectrometry. A vibrational fine structure in the effective ion yield curves, at threshold energies for the formation of these ions through OH-bond cleavage, has been observed. This vibrational progression has been assigned to the nu (OH) stretching mode, It has been supposed that the formation of these ions occurs by a predissociation of the vibrationally excited ground state of the parent anion. (C) 2001 Elsevier Science B.V.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QC Physics | ||||
Journal or Publication Title: | INTERNATIONAL JOURNAL OF MASS SPECTROMETRY | ||||
Publisher: | ELSEVIER SCIENCE BV | ||||
ISSN: | 1387-3806 | ||||
Official Date: | 20 February 2001 | ||||
Dates: |
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Volume: | 205 | ||||
Number: | 1-3 Sp. Iss. SI | ||||
Number of Pages: | 17 | ||||
Page Range: | pp. 119-135 | ||||
Publication Status: | Published |
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