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Control of metal/ligand stoichiometry and structure in aminopyridinato complexes of zirconium: N-alkyl is better than trimethylsilyl
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UNSPECIFIED (2000) Control of metal/ligand stoichiometry and structure in aminopyridinato complexes of zirconium: N-alkyl is better than trimethylsilyl. CHEMICAL COMMUNICATIONS (21). pp. 2099-2100. ISSN 1359-7345.
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Abstract
N-Adamantyl-2-aminopyridines (HL) readily form C-2-symmetric aminopyridinato complexes with zirconium [ZrL2X2] (X = Cl, NMe2, CH2Ph, CH2But) which are stable with respect to ligand redistribution and lead to catalysts for ethylene polymerisation with similar productivity to the related [Zr(benzamidinate)(2)X-2] system.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | CHEMICAL COMMUNICATIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 1359-7345 | ||||
Official Date: | 2000 | ||||
Dates: |
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Number: | 21 | ||||
Number of Pages: | 2 | ||||
Page Range: | pp. 2099-2100 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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