The Library
Crown ether complexation of Te(IV): formation and crystal structure of [(18-crown-6)Te(Cl)(mu-O)(2)Te(Cl)(18-crown-6)][SbCl6](2)
Tools
UNSPECIFIED (2000) Crown ether complexation of Te(IV): formation and crystal structure of [(18-crown-6)Te(Cl)(mu-O)(2)Te(Cl)(18-crown-6)][SbCl6](2). POLYHEDRON, 19 (15). pp. 1799-1802. ISSN 0277-5387.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Abstract
The product isolated as colourless crystals from the reaction system TeCl4-SbCl5-18-crown-6-MeCN has been identified (X-ray diffraction studies) as the ionic salt [(18-crown-6)Te(Cl)(mu-O)(2)Te(Cl)(18-crown-6)][SbCl6](2). The mu-oxo-bridged cations have a centre of inversion and feature a distorted eight-coordinate metal environment involving two bridging oxygen atoms (Te-O 1.960(4) Angstrom), one terminal chlorine atom (Te-CI 2.361(2) A) and five of the six oxygen atoms of the crown ligand (Te-O 2.549(4)-2.886(5) Angstrom). The question of stereochemical involvement of the lone pair of electrons associated with each Te(IV) centre is considered. (C) 2000 Elsevier Science Ltd. All rights reserved.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | POLYHEDRON | ||||
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
ISSN: | 0277-5387 | ||||
Official Date: | 30 July 2000 | ||||
Dates: |
|
||||
Volume: | 19 | ||||
Number: | 15 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 1799-1802 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |