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Encapsulated Tl(III) strongly retained within an iminophenolate cryptand host
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UNSPECIFIED (2000) Encapsulated Tl(III) strongly retained within an iminophenolate cryptand host. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 8 . pp. 1275-1278. ISSN 0300-9246.
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Abstract
The crystal structure of a thallium(III) iminophenolate cryptate is reported. Tl(III) is strongly held within the host, as judged by NMR indicators of strength of binding, by both imino-N, (via Tl-203,Tl-205,N-15 coupling of over 1000 Hz in the MAS-CP spectrum) and phenolate-O donors (via the weakness of competitive H-bonding to the phenolate O- groups, seen in the solution H-1 spectrum).
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 0300-9246 | ||||
Official Date: | 2000 | ||||
Dates: |
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Volume: | 8 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 1275-1278 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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