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Synthesis of the terpyridyl pendant-arm azamacrocycle 4 '-(p-1,4,7-triazacyclonon-1-ylmethylphenyl)-2,2 ': 6 ',2 ''-terpyridine (L) and complexes of L with copper(II) and nickel(II). Crystal structure of [Cu(HL)(H2O)(2)][PF6](3)
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UNSPECIFIED (2000) Synthesis of the terpyridyl pendant-arm azamacrocycle 4 '-(p-1,4,7-triazacyclonon-1-ylmethylphenyl)-2,2 ': 6 ',2 ''-terpyridine (L) and complexes of L with copper(II) and nickel(II). Crystal structure of [Cu(HL)(H2O)(2)][PF6](3). JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (4). pp. 441-444. ISSN 0300-9246.
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Abstract
The azamacrocyclic ligand 4'-(p-1,4,7-triazacyclonon-1-ylmethylphenyl)-2,2':6',2 "-terpyridine (L) has been prepared, and some of the complexes it forms with hydrated copper(II) and nickel(II) have been isolated as the [PF6](-) salts. X-Ray crystallography has been used to determine the solid state structure of the distorted trigonal bipyramidal complex [Cu(HL)(H2O)(2)][PF6](3), in which the copper(II) is co-ordinated to the terpyridyl group and the azamacrocycle is monoprotonated and non-co-ordinating. A bis(2,2':6',2 "-terpyridine)nickel(II) complex, [Ni(H2L2)(2)][PF6](6) has also been isolated, in which each azamacrocycle is diprotonated.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 0300-9246 | ||||
Official Date: | 2000 | ||||
Dates: |
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Number: | 4 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 441-444 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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