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Steric constraint generating large through-space H-1-Tl-203,Tl-205 coupling in a dithallium(I) cryptate
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UNSPECIFIED (2000) Steric constraint generating large through-space H-1-Tl-203,Tl-205 coupling in a dithallium(I) cryptate. CHEMICAL COMMUNICATIONS (1). pp. 21-22. ISSN 1359-7345.
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Abstract
An aminocryptand host enforces approach of encapsulated Tl(I) ions to just within 4.4 Angstrom; despite this relatively large separation, strong Tl(i)... Tl(i) interaction is observed and the aromatic proton of the bridging link exhibits a large through-space coupling to the pair of equivalent Tl nuclei.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | CHEMICAL COMMUNICATIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 1359-7345 | ||||
Official Date: | 2000 | ||||
Dates: |
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Number: | 1 | ||||
Number of Pages: | 2 | ||||
Page Range: | pp. 21-22 | ||||
Publication Status: | Published |
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