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Efficient room temperature copper(I) mediated 5-endo radical cyclisations
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UNSPECIFIED (1999) Efficient room temperature copper(I) mediated 5-endo radical cyclisations. TETRAHEDRON LETTERS, 40 (49). pp. 8619-8623. ISSN 0040-4039.
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Abstract
Reaction of bromo-enamides with catalytic Cu(Me-6-trien)Br at room temperature furnishes regioisomeric mixtures of unsaturated pyrrolidinones in a highly efficient manner via an initial 5-endo radical cyclisation reaction followed by an oxidation and elimination of H+. Bromo-enamide 3f furnishes the beta-lactam via a 4-exo cyclisation pathway. (C) 1999 Elsevier Science Ltd. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | TETRAHEDRON LETTERS | ||||
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
ISSN: | 0040-4039 | ||||
Official Date: | 3 December 1999 | ||||
Dates: |
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Volume: | 40 | ||||
Number: | 49 | ||||
Number of Pages: | 5 | ||||
Page Range: | pp. 8619-8623 | ||||
Publication Status: | Published |
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