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Adsorption site and orientation of pyridine on Cu{110} determined by photoelectron diffraction
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UNSPECIFIED (1999) Adsorption site and orientation of pyridine on Cu{110} determined by photoelectron diffraction. JOURNAL OF CHEMICAL PHYSICS, 110 (19). pp. 9666-9672. ISSN 0021-9606.
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Abstract
The local adsorption geometry of pyridine on Cu{110} has been determined quantitatively using photoelectron diffraction in the scanned-energy mode. At high coverages the molecule adsorbs nearly atop a Cu atom in the close-packed rows with a N-Cu bond length of 2.00 Angstrom. Moreover, the Cu-N axis and the molecular (C-2) axis are inclined by 8 degrees and 20 degrees, respectively, to the surface normal. The result shows that not only the adsorption site of the emitter (in this case the N atom) but also the position of relatively light scatterers (the C atoms) can be determined by photoelectron diffraction. (C) 1999 American Institute of Physics. [S0021-9606(99)70119-4].
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QC Physics | ||||
Journal or Publication Title: | JOURNAL OF CHEMICAL PHYSICS | ||||
Publisher: | AMER INST PHYSICS | ||||
ISSN: | 0021-9606 | ||||
Official Date: | 15 May 1999 | ||||
Dates: |
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Volume: | 110 | ||||
Number: | 19 | ||||
Number of Pages: | 7 | ||||
Page Range: | pp. 9666-9672 | ||||
Publication Status: | Published |
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