The Library
Halide abstraction reactions of tin(IV) chloride and the group 3 chlorides MCl3 (M = Sc, Y, La) in thf: Crystal and molecular structure of [ScCl2(thf)(4)SnCl5(thf)]
Tools
UNSPECIFIED (1998) Halide abstraction reactions of tin(IV) chloride and the group 3 chlorides MCl3 (M = Sc, Y, La) in thf: Crystal and molecular structure of [ScCl2(thf)(4)SnCl5(thf)]. TRANSITION METAL CHEMISTRY, 23 (4). pp. 387-390. ISSN 0340-4285.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Abstract
Direct treatment (1:1) of MCl3 (M = Sc, Y or La) with SnCl4 in thf provides colourless compounds of the type ScSnCl7(thf)(5) and MSnCl7(thf)(6) (M = Y, La), which have been characterised by elemental analysis and spectroscopic studies. An X-ray determination of ScSnCl7(thf)(5) reveals an ionic structure comprising individual six-coordinate [ScCl2(thf)(4)](+) cations and [SnCl5(thf)](-) anions. The cations feature an octahedral metal geometry in which a linear Cl-Sc-Cl unit is surrounded by an equatorial girdle of four solvent (thf) molecules.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | TRANSITION METAL CHEMISTRY | ||||
Publisher: | KLUWER ACADEMIC PUBL | ||||
ISSN: | 0340-4285 | ||||
Official Date: | August 1998 | ||||
Dates: |
|
||||
Volume: | 23 | ||||
Number: | 4 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 387-390 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |