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Synthesis and molecular structure of the lithiated triamidoamine [Li-3{N((CH2CH2SiBuMe2)-Me-t)(3)}(THF)(n)]
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UNSPECIFIED (1998) Synthesis and molecular structure of the lithiated triamidoamine [Li-3{N((CH2CH2SiBuMe2)-Me-t)(3)}(THF)(n)]. INORGANIC CHEMISTRY, 37 (13). 3435-+. ISSN 0020-1669.
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Abstract
Addition of THF to a pentane solution of [Li-3{N((CH2CH2SiBuMe2)-Me-t)(3)}] prepared in situ from tris-(2-aminoethyl)amine (TREN) leads to the crystallization of [Li-3{N((CH2CH2SiBuMe2)-Me-t)(3)}(THF)(n)] (n = 3). The molecular structure of the compound (n = 2) reveals a dimeric structure as shown. Two triamidoamine ligands are linked via incorporation of one amido nitrogen atom each into a Li2N2 Unit. Sublimation of the above allows isolation of the base-free compound [Li-3{N((CH2CH2SiBuMe2)-Me-t)(3)}].
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | INORGANIC CHEMISTRY | ||||
Publisher: | AMER CHEMICAL SOC | ||||
ISSN: | 0020-1669 | ||||
Official Date: | 29 June 1998 | ||||
Dates: |
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Volume: | 37 | ||||
Number: | 13 | ||||
Number of Pages: | 3 | ||||
Page Range: | 3435-+ | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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