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alpha,omega-dicarboxyl telechelic poly(methyl methacrylate) via radical addition-fragmentation polymerization
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UNSPECIFIED (1998) alpha,omega-dicarboxyl telechelic poly(methyl methacrylate) via radical addition-fragmentation polymerization. POLYMER, 39 (14). pp. 3119-3128. ISSN 0032-3861.
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Abstract
Catalytic chain transfer polymerization of benzyl methacrylate leads to a mixture of poly(benzyl methacrylate) macromonomers. Benzyl methacrylate dimer macromonomer has been isolated as a pure compound and used as a radical addition fragmentation chain transfer agent. This results in poly(methyl methacrylate) with both alpha and omega terminal benzyl methacrylate units. Catalytic hydrogenation of alpha,omega-benzyl methacrylate terminal poly(methyl methacrylate) results in evolution of toluene and formation of alpha,omega-dicarboxyl functional telechelic poly(methyl methacrylate). The products have been fully characterized by matrix assisted laser desorption time-of-flight mass spectrometry in conjunction with H-1 and C-13 n.m.r. spectroscopy. (C) 1998 Elsevier Science Ltd. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | POLYMER | ||||
Publisher: | ELSEVIER SCI LTD | ||||
ISSN: | 0032-3861 | ||||
Official Date: | June 1998 | ||||
Dates: |
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Volume: | 39 | ||||
Number: | 14 | ||||
Number of Pages: | 10 | ||||
Page Range: | pp. 3119-3128 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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