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The Heck olefination reaction; A DFT study of the elimination pathway
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UNSPECIFIED (1998) The Heck olefination reaction; A DFT study of the elimination pathway. TETRAHEDRON LETTERS, 39 (20). pp. 3229-3232. ISSN 0040-4039.
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Abstract
Theoretical studies of the pathway in the Heck reaction between ethene and a methyl electrophile at [Pd(H(2)ACH(2)AH(2))(CH3)(H2C=CH2)](+) (A = P, N) reveal intermediates with an agostic H which is the one preferentially transferred to base. (C) 1998 Elsevier Science Ltd. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | TETRAHEDRON LETTERS | ||||
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
ISSN: | 0040-4039 | ||||
Official Date: | 14 May 1998 | ||||
Dates: |
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Volume: | 39 | ||||
Number: | 20 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 3229-3232 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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