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A cis-octahedral dichloro complex of Fe-III with a tetradentate dipyridyl-diamino ligand
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UNSPECIFIED (1997) A cis-octahedral dichloro complex of Fe-III with a tetradentate dipyridyl-diamino ligand. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 53 (Part 10). pp. 1385-1387. ISSN 0108-2701.
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Abstract
In [N,N'-bis(2-pyridylmethyl)-1, 3-propanediamine-N,N',N '',N''']dichloroiron(III) perchlorate, [FeCl2(C15H20N4)]ClO4, the linear tetradentate Ligand adopts the cis-beta configuration which provides a favourable geometry for the six-membered chelate ring. The Fe-N distances show lengthening from the trans influence of the chloride ligands, with Fe-N-py values of 2.152 (3) and 2.179 (3) Angstrom, and Fe-N-amine distances of 2.141 (4) and 2.178 (4) Angstrom.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | ||||
Publisher: | MUNKSGAARD INT PUBL LTD | ||||
ISSN: | 0108-2701 | ||||
Official Date: | 15 October 1997 | ||||
Dates: |
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Volume: | 53 | ||||
Number: | Part 10 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 1385-1387 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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