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Substituent effects on the cyclo-manganation reaction - X-ray crystal structure of Mn{2-(Bu-n-N=CH)5-(NO2)C6H3}(CO)(4)
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UNSPECIFIED (1997) Substituent effects on the cyclo-manganation reaction - X-ray crystal structure of Mn{2-(Bu-n-N=CH)5-(NO2)C6H3}(CO)(4). JOURNAL OF ORGANOMETALLIC CHEMISTRY, 530 (1-2). pp. 19-25. ISSN 0022-328X.
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Abstract
The cyclometallation reaction between methylmanganese pentacarbonyl and a number of Schiffs bases has been studied. The dependence of the rate of reaction upon ligand substituents has been investigated, demonstrating a rare enhancement with more electron-rich ligands.
The X-ray structure of Mn{2-(Bu-n-N=CH)5-(NO2)C6H3}(CO)(4) has been determined.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF ORGANOMETALLIC CHEMISTRY | ||||
Publisher: | ELSEVIER SCIENCE SA LAUSANNE | ||||
ISSN: | 0022-328X | ||||
Official Date: | 1 March 1997 | ||||
Dates: |
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Volume: | 530 | ||||
Number: | 1-2 | ||||
Number of Pages: | 7 | ||||
Page Range: | pp. 19-25 | ||||
Publication Status: | Published |
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