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Metallacycles of the imidoylamidinato compounds HNC(R)NC(R)NH and Group 13 elements. Crystal structure of the complex [GaMe(2){HNC(CF3)NC(CF3)NH}]
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UNSPECIFIED (1997) Metallacycles of the imidoylamidinato compounds HNC(R)NC(R)NH and Group 13 elements. Crystal structure of the complex [GaMe(2){HNC(CF3)NC(CF3)NH}]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (6). pp. 909-910. ISSN 0300-9246.
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Abstract
Reaction of trimethylgallium with trifluoroacetamidine [H2NC(CF3)NH] resulted in an unusual elimination reaction, and yielded the air-stable volatile metallacycle [GaMe(2){HNC(CF3)NC(CF3)NH}] which shows a planar six-membered (GaNCNCN) ring; a related aluminium system. [AlMe(2){HNC(Ph)NC(Ph)NH}] was formed using benzamidine [H2NC(Ph)NH].
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 0300-9246 | ||||
Official Date: | 21 March 1997 | ||||
Dates: |
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Number: | 6 | ||||
Number of Pages: | 2 | ||||
Page Range: | pp. 909-910 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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