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Azamacrocyclic stabilization of SbCl2+: Synthesis and crystal structure of [SbCl2(Me(3)[9]aneN(3))][SbCl6] showing explicit Sb-III lone-pair stereochemical activity. Me(3)[9]aneN(3)=1,4,7-trimethyl-1,4,7-triazacyclononane
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UNSPECIFIED (1996) Azamacrocyclic stabilization of SbCl2+: Synthesis and crystal structure of [SbCl2(Me(3)[9]aneN(3))][SbCl6] showing explicit Sb-III lone-pair stereochemical activity. Me(3)[9]aneN(3)=1,4,7-trimethyl-1,4,7-triazacyclononane. POLYHEDRON, 15 (24). pp. 4497-4500. ISSN 0277-5387.
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Abstract
The reaction of antimony(III)chloride and antimony(V)chloride in acetonitrile in the presence of the azamacrocyclic ligand Me(3)[9]aneN(3) provides the golden-yellow ionic compound [SbCl2(Me(3)[9]aneN(3)][SbCl6]. X-ray structural characterization reveals the cation as five-coordinate with psi-octahedral metal geometry featuring a cis-SbCl2+ unit coordinated to the three donor nitrogen atoms of the ligand (fac) and a stereochemically active lone pair occupying the sixth site in a trans-position to a ring nitrogen atom. Copyright (C) 1996 Elsevier Science Ltd
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | POLYHEDRON | ||||
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
ISSN: | 0277-5387 | ||||
Official Date: | 1996 | ||||
Dates: |
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Volume: | 15 | ||||
Number: | 24 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 4497-4500 | ||||
Publication Status: | Published |
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