The Library
A copper(II) complex of a macrocyclic Schiff base ligand with a polyether bridge
Tools
UNSPECIFIED (1996) A copper(II) complex of a macrocyclic Schiff base ligand with a polyether bridge. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 52 (Part 5). pp. 1134-1136. ISSN 0108-2701.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Abstract
In the structure of aquachloro[7,10,13-trioxa-3,17,23-triazabicyclo[17.3.1]tricosa-1 (23),2,17,19,21-pentaene-N,N',N '']copper(II) hexafluorophosphate acetonitrile solvate, the Cu-II ion is pentacoordinate with square-pyramidal coordination geometry, with a relatively long axial bond to water [2.244 (5) Angstrom] and with the shortest Cu-N bond being to the pyridine N atom. The water molecule is also hydrogen bonded to two O atoms of the ligand. the complex is folded about the N-Cu-N axis, the polyether chain being nearly planar and making an angle of about 135 degrees with the pyridine ring.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | ||||
Publisher: | MUNKSGAARD INT PUBL LTD | ||||
ISSN: | 0108-2701 | ||||
Official Date: | 15 May 1996 | ||||
Dates: |
|
||||
Volume: | 52 | ||||
Number: | Part 5 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 1134-1136 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |