The Library
The potential of sulfimides as chiral acyl anion equivalents
Tools
UNSPECIFIED (1996) The potential of sulfimides as chiral acyl anion equivalents. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 (4). pp. 313-317. ISSN 0300-922X.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Abstract
Reaction of the tosyl imides 6 and 8 of 1,3-dithiane and 1,3,5-trithiane with sodium hydride and alkyl iodides in DMF yields anti alkylated products in all cases, In the case of the trithiane imide 8, both mono- and di-alkylation is observed, Preparation of cyclic sulfimide analogues of Eliel's oxathiane is shown to be problematic, but a new class of O,S-acetals, namely 4-bromophenylthiomethyl (BPTM) ethers, is introduced as a replacement for their troublesome phenylthiomethyl (PTM) analogues.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 0300-922X | ||||
Official Date: | 21 February 1996 | ||||
Dates: |
|
||||
Number: | 4 | ||||
Number of Pages: | 5 | ||||
Page Range: | pp. 313-317 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |