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ON THE REACTIONS OF [RUCL2(PPH3)3] WITH THIA CROWN ETHERS - MOLECULAR-STRUCTURES OF [RUCL2(PPH3)([9]ANES3)] ([9]ANES3 = 1,4,7-TRITHIACYCLONONANE) AND [RUCL(PPH3)([14]ANES4)CLO4 ([14]ANES4 = 1,4,8,11-TETRATHIACYCLOTETRADECANE)
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UNSPECIFIED (1993) ON THE REACTIONS OF [RUCL2(PPH3)3] WITH THIA CROWN ETHERS - MOLECULAR-STRUCTURES OF [RUCL2(PPH3)([9]ANES3)] ([9]ANES3 = 1,4,7-TRITHIACYCLONONANE) AND [RUCL(PPH3)([14]ANES4)CLO4 ([14]ANES4 = 1,4,8,11-TETRATHIACYCLOTETRADECANE). JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (7). pp. 1131-1135. ISSN 0300-9246.
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Abstract
The reaction of [RuCl2(PPh3)3] with 1,4,7-trithiacyclononane ([9]aneS3) gives the neutral complex [RuCl2(PPh3)([9]aneS3)] while the same complex with 1,4,8,11-tetrathiacyclotetradecane ([14]aneS4) followed by chloride-perchlorate metathesis provides the salt cis-[RuCl(PPh3)([14]aneS4)]ClO4. The structures of both complexes have been determined by X-ray crystallography.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 0300-9246 | ||||
Official Date: | 7 April 1993 | ||||
Dates: |
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Number: | 7 | ||||
Number of Pages: | 5 | ||||
Page Range: | pp. 1131-1135 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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