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SYNTHESIS AND REACTIVITY OF BIS(ETA-1,4-DI-TERT-BUTYLBUTA-1,3-DIENE)COBALT - THE X-RAY CRYSTAL-STRUCTURE OF THE ANIONIC BUTADIENE SANDWICH COMPLEX [K(18-CROWN-6)(THF)2] [CO(ETA-C4H4BUT2)2]
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UNSPECIFIED (1993) SYNTHESIS AND REACTIVITY OF BIS(ETA-1,4-DI-TERT-BUTYLBUTA-1,3-DIENE)COBALT - THE X-RAY CRYSTAL-STRUCTURE OF THE ANIONIC BUTADIENE SANDWICH COMPLEX [K(18-CROWN-6)(THF)2] [CO(ETA-C4H4BUT2)2]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (3). pp. 248-250. ISSN 0022-4936.
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Abstract
Cocondensation of cobalt atoms with 1,4-di-tert-butylbuta-1,3-diene affords the stable, paramagnetic butadiene sandwich compound [Co(eta-C4H4But2)2], which is a reactive source of Co0 fragments; reduction Of [Co(eta-C4H4But2)2] with potassium affords the first crystallographically characterised homoleptic butadiene sandwich complex, [Co(eta-C4H4But2)2]-, in which the bonding is that of a genuine diene rather than a metallacyclopentene.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 0022-4936 | ||||
Official Date: | 7 February 1993 | ||||
Dates: |
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Number: | 3 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 248-250 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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