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Synthesis of a series of novel N,N-dialkyl-TsDPEN ligands and their application to enantioselective addition of dialkylzinc to benzaldehyde
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Martins, Jose E. D. and Wills, Martin (2008) Synthesis of a series of novel N,N-dialkyl-TsDPEN ligands and their application to enantioselective addition of dialkylzinc to benzaldehyde. Tetrahedron: Asymmetry, Vol.19 (No.10). pp. 1250-1255. doi:10.1016/j.tetasy.2008.04.020 ISSN 0957-4166.
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Official URL: http://dx.doi.org/10.1016/j.tetasy.2008.04.020
Abstract
A series of mono- and dialkylated derivatives of C2-symmetric N-tosyl-1,2-diphenylethylene diamines have been prepared and used as ligands for the enantiomeric control of the addition of diethylzinc to aldehydes. Addition products of up to 79% ee were formed. (C) 2008 Elsevier Ltd. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Ligands, Biosynthesis, Enantioselective catalysis, Benzaldehyde | ||||
Journal or Publication Title: | Tetrahedron: Asymmetry | ||||
Publisher: | Pergamon | ||||
ISSN: | 0957-4166 | ||||
Official Date: | 30 May 2008 | ||||
Dates: |
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Volume: | Vol.19 | ||||
Number: | No.10 | ||||
Number of Pages: | 6 | ||||
Page Range: | pp. 1250-1255 | ||||
DOI: | 10.1016/j.tetasy.2008.04.020 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Funder: | Brazil. Coordenação do Aperfeiçoamento de Pessoal de Nível Superior (CAPES) |
Data sourced from Thomson Reuters' Web of Knowledge
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