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Application of proline-functionalised 1,2-diphenylethane-1,2-diamine (DPEN) in asymmetric transfer hydrogenation of ketones
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Manville, Charles, Docherty, Gordon, Padda, Ranbir and Wills, Martin (2011) Application of proline-functionalised 1,2-diphenylethane-1,2-diamine (DPEN) in asymmetric transfer hydrogenation of ketones. European Journal of Organic Chemistry, 2011 (34). pp. 6893-6901. doi:10.1002/ejoc.201101164 ISSN 1434-193X.
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WRAP_9574780-ch-280915-201101164_eur._j._org._chem_aug_2011_corrected_submission (1).pdf - Accepted Version - Requires a PDF viewer. Download (683Kb) | Preview |
Official URL: http://dx.doi.org/10.1002/ejoc.201101164
Abstract
A series of enantiomerically pure ligands containing a combination of proline and DPEN groups have been prepared and employed in the asymmetric transfer hydrogenation of ketones. In the case of cyclic ketones, alcohols with ee values of up to 98 % were obtained.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Ketones, Hydrogenation, Ruthenium, Iridium, Peptides | ||||
Journal or Publication Title: | European Journal of Organic Chemistry | ||||
Publisher: | Wiley ; V.C.H Verlag | ||||
ISSN: | 1434-193X | ||||
Official Date: | 2011 | ||||
Dates: |
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Volume: | 2011 | ||||
Number: | 34 | ||||
Number of Pages: | 9 | ||||
Page Range: | pp. 6893-6901 | ||||
DOI: | 10.1002/ejoc.201101164 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Date of first compliant deposit: | 18 December 2015 | ||||
Date of first compliant Open Access: | 18 December 2015 | ||||
Funder: | Engineering and Physical Sciences Research Council (EPSRC), Rhodia Consumer Specialties Ltd. |
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