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[Rh{NC5H3-2,6-(CH2PtBu2)2}(PCy3)][BArF4] : a latent low-coordinate rhodium(I) PNP pincer compound
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Chaplin, Adrian B. and Weller, Andrew S. (2011) [Rh{NC5H3-2,6-(CH2PtBu2)2}(PCy3)][BArF4] : a latent low-coordinate rhodium(I) PNP pincer compound. Organometallics, Vol.30 (No.16). pp. 4466-4469. doi:10.1021/om2004964 ISSN 0276-7333.
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Official URL: http://dx.doi.org/10.1021/om2004964
Abstract
An expedient new route to the cationic [(PNPtBu)Rh(L)]+ metal fragments (PNPtBu = κ3-NC5H3-2,6-(CH2P tBu2)2; L = CO, acetone, ethene, MeCN, N2) by the synthesis of, then substitution of PCy3 in, [(PNPtBu)Rh(PCy3)][BArF4] is reported. This synthetic route also allows for the synthesis of the new dihydrogen complex [(PNPtBu)Rh(H2)][BArF4]. [(PNPR)Rh(PCy3)][BArF4] (R= Ph, Cy, Mes) are also reported, in which the PCy3 ligand is more tightly bound to the metal center.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Rhodium, Organometallic compounds, Biosynthesis, Ligands | ||||
Journal or Publication Title: | Organometallics | ||||
Publisher: | American Chemical Society | ||||
ISSN: | 0276-7333 | ||||
Official Date: | 22 August 2011 | ||||
Dates: |
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Volume: | Vol.30 | ||||
Number: | No.16 | ||||
Page Range: | pp. 4466-4469 | ||||
DOI: | 10.1021/om2004964 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Funder: | Engineering and Physical Sciences Research Council (EPSRC) |
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