The Library
Hydrothermal synthesis map of bismuth titanates
Tools
Sardar, Kripasindhu and Walton, Richard I. (2012) Hydrothermal synthesis map of bismuth titanates. Journal of Solid State Chemistry, Vol.189 . pp. 32-37. doi:10.1016/j.jssc.2012.01.017 ISSN 0022-4596.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Official URL: http://dx.doi.org/10.1016/j.jssc.2012.01.017
Abstract
The hydrothermal synthesis of four bismuth titanate materials from common bismuth and titanium precursors under hydrothermal conditions is described. Reaction of NaBiO3·2H2O and anatase TiO2 in concentrated NaOH solution at 240 °C is shown to produce perovskite and sillenite phases Na0.5Bi0.5TiO3 and Bi12TiO20, depending on the ratio of metal precursors used. When KOH solution is used and a 1:1 ratio of the same precursors, a pyrochlore Bi1.43Ti2O6(OH)0.29(H2O)0.66 is formed. The use of a mixture of HNO3 and NaOH is shown to facilitate the formation of the Aurivillius-type bismuth titanate Bi4Ti3O12. The phases have been isolated separately as phase-pure powders and profile refinement of powder X-ray diffraction data allows comparisons with comparable materials reported in the literature. Analysis of Bi LIII-edge X-ray absorption near edge structure (XANES) spectra of the materials shows the oxidation state of bismuth is +3 in all of the hydrothermally derived products.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Journal or Publication Title: | Journal of Solid State Chemistry | ||||
Publisher: | Academic Press | ||||
ISSN: | 0022-4596 | ||||
Official Date: | May 2012 | ||||
Dates: |
|
||||
Volume: | Vol.189 | ||||
Page Range: | pp. 32-37 | ||||
DOI: | 10.1016/j.jssc.2012.01.017 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |