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A lithium–organic framework with coordinatively unsaturated metal sites that reversibly binds water
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Osta, Racha El, Frigoli, Michel, Marrot, Jérôme, Guillou, Nathalie, Chevreau, Hubert, Walton, Richard I. and Millange, Franck (2012) A lithium–organic framework with coordinatively unsaturated metal sites that reversibly binds water. Chemical Communications, Vol.48 (No.86). pp. 10639-10641. doi:10.1039/c2cc35861a ISSN 1359-7345.
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Official URL: http://dx.doi.org/10.1039/C2CC35861A
Abstract
The synthesis and characterisation of a three-dimensional lithium–organic framework MIL-145 is described, which upon thermal treatment yields a second open framework, MIL-146, that contains four and three-coordinate lithium centres: the coordinatively unsaturated trigonal planar lithium centres are able to reversibly bind water with crystallinity maintained, while the dehydrated phase shows preferential adsorption of CO2 over N2.
Item Type: | Journal Article | ||||
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Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Journal or Publication Title: | Chemical Communications | ||||
Publisher: | Royal Society of Chemistry | ||||
ISSN: | 1359-7345 | ||||
Official Date: | 2012 | ||||
Dates: |
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Volume: | Vol.48 | ||||
Number: | No.86 | ||||
Page Range: | pp. 10639-10641 | ||||
DOI: | 10.1039/c2cc35861a | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
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