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Data for NMR-based assignment of isoleucine vs allo-isoleucine stereochemistry
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Fox, David J. (2017) Data for NMR-based assignment of isoleucine vs allo-isoleucine stereochemistry. [Dataset]
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Data for Isoleucine Paper.zip - Published Version Download (136Mb) |
Official URL: https://wrap.warwick.ac.uk/74515/
Abstract
A simple 1H and 13C NMR spectrometric analysis is demonstrated that permits differentiation of isoleucine and allo-isoleucine residues by inspection of the chemical shift and coupling constants of the signals associated with the proton and carbon at the α-stereocentre. This is applied to the estimation of epimerisation during metal-free N-arylation and peptide coupling reactions.
Item Type: | Dataset | |||||||||
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Subjects: | Q Science > QD Chemistry | |||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | |||||||||
Type of Data: | Experimental data | |||||||||
Library of Congress Subject Headings (LCSH): | Stereochemistry, Nuclear magnetic resonance spectroscopy, Peptides, Amino acids | |||||||||
Journal or Publication Title: | NMR-based assignment of isoleucine vs allo-isoleucine stereochemistry | |||||||||
Publisher: | University of Warwick, Department of Chemistry | |||||||||
Official Date: | 21 September 2017 | |||||||||
Dates: |
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Status: | Not Peer Reviewed | |||||||||
Publication Status: | Published | |||||||||
Media of Output (format): | .zip; .pdf; .txt; .par | |||||||||
Access rights to Published version: | Open Access (Creative Commons) | |||||||||
Description: | 700 MHz NMR |
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Date of first compliant deposit: | 21 September 2017 | |||||||||
Date of first compliant Open Access: | 22 September 2017 | |||||||||
RIOXX Funder/Project Grant: |
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Contributors: |
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