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Asymmetric hydrogenation of ketones using a ruthenium(II) catalyst containing BINOL-derived monodonor phosphorus-donor ligands
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UNSPECIFIED (2004) Asymmetric hydrogenation of ketones using a ruthenium(II) catalyst containing BINOL-derived monodonor phosphorus-donor ligands. ORGANIC LETTERS, 6 (22). pp. 4105-4107. doi:10.1021/ol0481840 ISSN 1523-7060.
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Official URL: http://dx.doi.org/10.1021/ol0481840
Abstract
A series of ruthenium(II) complexes containing BINOL-based monodonor phosphorus ligands have been prepared and applied to the asymmetric catalysis of the hydrogenation of aryl/alkyl ketones. The best ligands for this application are those which contain an aromatic groups with either a methoxide or bromide on the ortho position. Using these ligands, alcohols with ee's of up to 99% are formed.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | ORGANIC LETTERS | ||||
Publisher: | AMER CHEMICAL SOC | ||||
ISSN: | 1523-7060 | ||||
Official Date: | 28 October 2004 | ||||
Dates: |
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Volume: | 6 | ||||
Number: | 22 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 4105-4107 | ||||
DOI: | 10.1021/ol0481840 | ||||
Publication Status: | Published |
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