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A chloride-bridged chain polymer: synthesis and X-ray structure of [GdCl(mu-Cl)(2)(H2O)(2)CH3CN]
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UNSPECIFIED (2003) A chloride-bridged chain polymer: synthesis and X-ray structure of [GdCl(mu-Cl)(2)(H2O)(2)CH3CN]. Inorganica Chimica Acta, 353 . pp. 276-279. doi:10.1016/S0020-1693(03)00205-6 ISSN 0020-1693.
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Official URL: http://dx.doi.org/10.1016/S0020-1693(03)00205-6
Abstract
The title compound has been synthesised and its structure determined by X-ray diffraction. The structure comprises a single strand polymer, with five independent Gd units in the crystallographic asymmetric unit. Each gadolinium atom has eight-coordinate bicapped trigonal prismatic geometry, co-ordinated by one terminal chlorine atom, four bridging chlorine atoms, two water molecules and one acetonitrile. Linkage to neighbouring metal centres is by double halogen bridges. The mean co-ordination distances are: Gd-Cl 2.822 (bridging) and 2.676 Angstrom (terminal), Gd-O, 2.362 and Gd-N, 2.538 Angstrom. (C) 2003 Elsevier B.V. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | Inorganica Chimica Acta | ||||
Publisher: | ELSEVIER SCIENCE SA | ||||
ISSN: | 0020-1693 | ||||
Official Date: | 8 September 2003 | ||||
Dates: |
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Volume: | 353 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 276-279 | ||||
DOI: | 10.1016/S0020-1693(03)00205-6 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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