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Synthesis of carbonates and related compounds from carbon dioxide via methanesulfonyl carbonates
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UNSPECIFIED (2003) Synthesis of carbonates and related compounds from carbon dioxide via methanesulfonyl carbonates. JOURNAL OF ORGANIC CHEMISTRY, 68 (14). pp. 5439-5444. doi:10.1021/jo026753g ISSN 0022-3263.
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Official URL: http://dx.doi.org/10.1021/jo026753g
Abstract
Carbonate anions resulting from reaction of primary or secondary alcohols with carbon dioxide, when added to methanesulfonic anhydride in cooled acetonitrile solution, yield methanesulfonyl carbonates, a new class of synthetic intermediate. Base-mediated reaction of the methanesulfonyl carbonates with alcohols, thiols, and amines yields carbonates, thiocarbonates, and carbamates, respectively. Overall yields for the three steps vary from 19% to 42%.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF ORGANIC CHEMISTRY | ||||
Publisher: | AMER CHEMICAL SOC | ||||
ISSN: | 0022-3263 | ||||
Official Date: | 11 July 2003 | ||||
Dates: |
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Volume: | 68 | ||||
Number: | 14 | ||||
Number of Pages: | 6 | ||||
Page Range: | pp. 5439-5444 | ||||
DOI: | 10.1021/jo026753g | ||||
Publication Status: | Published |
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