Chaplin, Adrian B., Hooper, Joel F., Weller, Andrew S. and Willis, Michael C.. (2012) Intermolecular hydroacylation : high activity rhodium catalysts containing small-bite-angle diphosphine ligands. Journal of the American Chemical Society, Vol.134 (No.10). pp. 4885-4897. ISSN 0002-7863

Pike, Sebastian D., Pawley, R, Chaplin, Adrian B., Thompson, Amber L., Hooper, Joel A., Willis, Michael C. and Weller, Andrew S.. (2011) Exploring (Ph2PCH2CH2)2E ligand space (E = O, S, PPh) in RhI alkene complexes as potential hydroacylation catalysts. European Journal of Inorganic Chemistry, Vol.2011 (No.36). pp. 5558-5565. ISSN 1434-1948

Chaplin, Adrian B. and Weller, Andrew S.. (2011) A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H : an intermediate in the dehydrocoupling of H3B·NMe2H. Acta Crystallographica. Section C: Crystal Structure Communications, Vol.67 (No.11). m355-m358. ISSN 0108-2701

Chaplin, Adrian B., Green, J. C. (Jennifer C.) and Weller, Andrew S.. (2011) C–C activation in the solid state in an organometallic σ-complex. Journal of the American Chemical Society, Vol.133 (No.33). pp. 13162-13168. ISSN 0002-7863

Chaplin, Adrian B. and Weller, Andrew S.. (2011) [Rh{NC5H3-2,6-(CH2PtBu2)2}(PCy3)][BArF4] : a latent low-coordinate rhodium(I) PNP pincer compound. Organometallics, Vol.30 (No.16). pp. 4466-4469. ISSN 0276-7333

Pontiggia, Ashley J., Chaplin, Adrian B. and Weller, Andrew S.. (2011) Cationic iridium complexes of the Xantphos ligand. Flexible coordination modes and the isolation of the hydride insertion product with an alkene. Journal of Organometallic Chemistry, Vol.696 (No.17). pp. 2870-2876. ISSN 0022-328X

Sewell, Laura J., Chaplin, Adrian B. and Weller, Andrew S.. (2011) Hydroboration of an alkene by amine–boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation. Dalton Transactions, Vol.40 (No.29). pp. 7499-7501. ISSN 1477-9226

Johnson, Heather C., Robertson, Alasdair P. M., Chaplin, Adrian B., Sewell, Laura J., Thompson, Amber L., Haddow, Mairi F., Manners, Ian, 1961- and Weller, Andrew S.. (2011) Catching the first oligomerization event in the catalytic formation of polyaminoboranes : H3B·NMeHBH2·NMeH2 bound to iridium. Journal of the American Chemical Society, Vol.133 (No.29). pp. 11076-11079. ISSN 0002-7863

Dallanegra, Romaeo, Pilgrim, Ben S., Chaplin, Adrian B., Donohoe, Timothy J. and Weller, Andrew S.. (2011) Dehydrogenation of cyclic thioethers bound to a [Rh(diphosphine)]+ fragment. Dalton Transactions, Vol.40 (No.25). pp. 6626-6628. ISSN 1477-9226

Chaplin, Adrian B. and Dyson, Paul J.. (2011) Influence of arene dissociation and phosphine coordination on the catalytic activity of [RuCl(κ2-triphos)(p-cymene)]PF6. Journal of Organometallic Chemistry, Vol.696 (No.13). pp. 2485-2490. ISSN 0022-328X

González-Rodríguez, Carlos, Pawley, Rebekah J., Chaplin, Adrian B., Thompson, Amber L., Weller, Andrew S. and Willis, Michael C.. (2011) Rhodium-catalyzed branched-selective alkyne hydroacylation : a ligand-controlled regioselectivity switch. Angewandte Chemie International Edition, Vol.50 (No.22). pp. 5134-5138. ISSN 1433-7851

Dallanegra, Romaeo, Robertson, Alasdair P. M., Chaplin, Adrian B., Manners, Ian, 1961- and Weller, Andrew S.. (2011) Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes. Chemical Communications, Vol.47 (No.13). pp. 3763-3765. ISSN 1359-7345

Woolf, Anthony, Chaplin, Adrian B., McGrady, John E., Alibadi, Muhsen A. M., Rees, Nicholas H., Draper, Sylvia, Murphy, F. (Frances) and Weller, Andrew S.. (2011) {Rh(PiBu3)2}+ fragments ligated to arenes : from benzene to polyaromatic hydrocarbons, part I - an experimental approach. European Journal of Inorganic Chemistry, Vol.2011 (No.10). pp. 1614-1625. ISSN 1434-1948

Woolf, Anthony, Alibadi, Muhsen A. M., Chaplin, Adrian B., McGrady, J. E. (John E.) and Weller, Andrew S.. (2011) {Rh(PiBu3)2}+ fragments ligated to arenes : from benzene to polyaromatic hydrocarbons, part II - computational analysis of pathways for haptotropic migration. European Journal of Inorganic Chemistry, Vol.2011 (No.10). pp. 1626-1634. ISSN 1434-1948

Stevens, Charlotte J., Dallanegra, Romaeo, Chaplin, Adrian B., Weller, Andrew S., Macgregor, Stuart A., Ward, B. (Bryan), McKay, D. (David), Alcaraz, Gilles and Sabo-Etienne, Sylviane. (2011) [Ir(PCy(3))(2)(H)(2)(H(2)B-NMe(2))](+) as a latent source of aminoborane : probing the role of metal in the dehydrocoupling of H(3)B center dot NMe(2)H and retrodimerisation of [H(2)BNMe(2)](2). Chemistry: A European Journal, Vol.17 (No.10). pp. 3011-3020. ISSN 0947-6539

Alcaraz, Gilles, Chaplin, Adrian B., Stevens, Charlotte J., Clot, Eric, Vendier, Laure, Weller, Andrew S. and Sabo-Etienne, Sylviane. (2010) Ruthenium, rhodium, and iridium bis(σ-B−H) diisopropylaminoborane complexes. Organometallics, Vol.29 (No.21). pp. 5591-5595. ISSN 0276-7333

Chaplin, Adrian B. and Weller, Andrew S.. (2010) [B(3,5-C6H3Cl2)4]- as a useful anion for organometallic chemistry. European Journal of Inorganic Chemistry, Vol.2010 (No.32). pp. 5124-5128. ISSN 1434-1948

Sparkes, Hazel A., Chaplin, Adrian B., Weller, Andrew S. and Howard, J. A. K.. (2010) Bond catastrophes in rhodium complexes : experimental charge-density studies of [Rh(C7H8)(PtBu3)Cl] and [Rh(C7H8)(PCy3)Cl]. Acta Crystallographica. Section B: Structural Science, Vol.66 (No.5). pp. 503-514. ISSN 0108-7681

Sewell, Laura J., Chaplin, Adrian B., Abdallah, Joseph A. B. and Weller, Andrew S.. (2010) Reversible C–H activation of a PtBuiBu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation. Dalton Transactions, Vol.39 (No.32). pp. 7437-7439. ISSN 1477-9226

Townsend, Nell S., Chaplin, Adrian B., Naser, M. Abu, Thompson, Amber L., Rees, Nicholas H., Macgregor, Stuart A. and Weller, Andrew S.. (2010) Reactivity of the latent 12-electron fragment [Rh(PiBu3)2]+ with aryl bromides : aryl-Br and phosphine ligand C-H activation. Chemistry: A European Journal, Vol.16 (No.28). pp. 8376-8389. ISSN 0947-6539

Chaplin, Adrian B., Tonner, Ralf and Weller, Andrew S.. (2010) Isolation of a low-coordinate rhodium phosphine complex formed by C−C bond activation of biphenylene. Organometallics, Vol.29 (No.12). pp. 2710-2714. ISSN 0276-7333

Chaplin, Adrian B. and Weller, Andrew S.. (2010) C−C bond activation of a cyclopropyl phosphine : isolation and reactivity of a tetrameric rhodacyclobutane. Organometallics, Vol.29 (No.10). pp. 2332-2342. ISSN 0276-7333

Dallanegra, Romaeo, Chaplin, Adrian B., Tsim, Jennifer and Weller, Andrew S.. (2010) Amino-borane oligomers bound to a Rh(i) metal fragment. Chemical Communications, Vol.46 (No.18). pp. 3092-3094. ISSN 1359-7345

Pawley, Rebekah J., Moxham, Gemma L., Dallanegra, Romaeo, Chaplin, Adrian B., Brayshaw, Simon K., Weller, Andrew S. and Willis, Michael C.. (2010) Controlling selectivity in intermolecular alkene or aldehyde hydroacylation reactions catalyzed by {Rh(L2)}+ fragments. Organometallics, Vol.29 (No.7). pp. 1717-1728. ISSN 0276-7333

Moret, Séverine, Dallanegra, Romaeo, Chaplin, Adrian B., Douglas, Thomas M., Hiney, Rachel M. and Weller, Andrew S.. (2010) Alkyl dehydrogenation in iridium tri-cyclopentyl phosphines. Inorganica Chimica Acta, Vol.363 (No.3). pp. 574-580. ISSN 0020-1693

Chaplin, Adrian B. and Weller, Andrew S.. (2010) Amine− and dimeric amino−borane complexes of the {Rh(PiPr3)2}+ fragment and their relevance to the transition-metal-mediated dehydrocoupling of amine−boranes. Inorganic Chemistry, Vol.49 (No.3). pp. 1111-1121. ISSN 0020-1669

Hiney, Rachel M., Chaplin, Adrian B., Harmer, Jeffrey, Green, Jennifer C. and Weller, Andrew S.. (2010) Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count : [Rh6(PCy3)6H12]+ and [Rh6(PCy3)6H14]+. Dalton Transactions, Vol.39 (No.7). pp. 1726-1733. ISSN 1477-9226

Douglas, Thomas M., Chaplin, Adrian B., Weller, Andrew S., Yang, Xinzheng and Hall, Michael B.. (2009) Monomeric and oligomeric amine−borane σ-complexes of rhodium. Intermediates in the catalytic dehydrogenation of amine−boranes. Journal of the American Chemical Society, Vol.131 (No.42). pp. 15440-15456. ISSN 0002-7863

Dallanegra, Romaeo, Chaplin, Adrian B. and Weller, Andrew S.. (2009) Bis(σ-amine-borane) complexes : an unusual binding mode at a transition-metal center. Angewandte Chemie International Edition, Vol.48 (No.37). pp. 6875-6878. ISSN 1433-7851

Tang, Christina Y., Smith, W. (William), Vidovic, Dragoslav, Thompson, Amber L., Chaplin, Adrian B. and Aldridge, S. (Simon). (2009) Sterically encumbered iridium bis(N-heterocyclic carbene) systems : multiple C−H activation processes and isomeric normal/abnormal carbene complexes. Organometallics, Vol.28 (No.10). pp. 3059-3066. ISSN 0276-7333

Chaplin, Adrian B., Poblador-Bahamonde, Amalia I., Sparkes, Hazel A., Howard, J. A. K., Macgregor, Stuart A. and Weller, Andrew S.. (2009) Alkyl dehydrogenation in a Rh(i) complex via an isolated agostic intermediate. Chemical Communications (No.2). pp. 244-246. ISSN 1359-7345

Chaplin, Adrian B. and Weller, Andrew S.. (2009) B-H activation at a rhodium(I) center : isolation of a bimetallic complex relevant to the transition-metal-catalyzed dehydrocoupling of amine-boranes. Angewandte Chemie International Edition, Vol.49 (No.3). pp. 581-584. ISSN 1433-7851

Douglas, Thomas M., Chaplin, Adrian B. and Weller, Andrew S.. (2008) Amine-borane σ-complexes of rhodium. Relevance to the catalytic dehydrogenation of amine-boranes. Journal of the American Chemical Society, Vol.130 (No.44). pp. 14432-14433. ISSN 0002-7863

Douglas, Thomas M., Chaplin, Adrian B. and Weller, Andrew S.. (2008) Dihydrogen loss from a 14-electron rhodium(III) bis-phosphine dihydride to give a rhodium(I) complex that undergoes oxidative addition with aryl chlorides. Organometallics, Vol.27 (No.13). pp. 2918-2921. ISSN 0276-7333

Chaplin, Adrian B., Béni, Zoltán, Hartinger, Christian G., Hamidane, Hisham Ben, Phillips, Andrew D., Scopelliti, Rosario and Dyson, Paul J.. (2008) Linked metal-cluster systems : isolation and characterisation of {anti-[(p-cymene)RuCl]-μ-[κ 2-P,P′;κ 1-P′′-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2. Journal of Cluster Science, Vol.19 (No.1). pp. 295-309. ISSN 1040-7278

Chaplin, Adrian B. and Dyson, Paul J.. (2008) Reactivity and catalytic activity of a robust ruthenium(II)−triphos complex. Inorganic Chemistry, Vol.47 (No.1). pp. 381-390. ISSN 0020-1669

Chaplin, Adrian B.. (2008) Catalytic activity of bis-phosphine ruthenium(II)-arene compounds. Chimia, Vol.62 (No.4). pp. 217-220. ISSN 0009-4293