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Number of items: 91.
2024
Hood, Thomas M., Lau, S. and Chaplin, Adrian B. (2024) Capture of mechanically interlocked molecules using rhodium-mediated terminal alkyne dimerisation. RSC Advances , 14 (11). pp. 7740-7744. doi:10.1039/D4RA00566J ISSN 2046-2069.
Sinclair, Matthew J. G., Roig, N., Gyton, Matthew R., Tsoureas, N., Cloke, F. G. N., Alonso, M. (Maria) and Chaplin, Adrian B. (2024) T-Shaped palladium and platinum {MNO}10 nitrosyl complexes. Inorganic Chemistry . doi:10.1021/acs.inorgchem.3c03434 ISSN 0020-1669. (In Press)
2023
KrΓ€mer, Tobias, Gyton, Matthew R., Bustos, I., Sinclair, M. J. G., Tan, Sze-yin, Wedge, C. J., Macgregor, S. A. and Chaplin, Adrian B. (2023) Stability and CβH bond activation reactions of palladium(I) and platinum(I) metalloradicals : carbon-to-metal H-atom transfer and an organometallic radical rebound mechanism. Journal of the American Chemical Society, 145 (25). pp. 14087-14100. doi:10.1021/jacs.3c04167 ISSN 0002-7863.
Emerson-King, Jack and Chaplin, Adrian B. (2023) Template synthesis of an intermediate in silver salt metathesis using a calix[4]arene-based diphosphine ligand. Dalton Transactions, 52 (16). pp. 5044-5046. doi:10.1039/D3DT00567D ISSN 1477-9226.
Emerson-King, Jack, Pan, Sudip, Gyton, Matthew R., Tonner-Zech, Ralf and Chaplin, Adrian B. (2023) Synthesis of a rhodium(III) dinitrogen complex using a calix[4]arene-based diphosphine ligand. Chemical Communications, 59 (15). pp. 2150-2152. doi:10.1039/D2CC06837K ISSN 1359-7345.
Poole, E. W., Bustos, I., Hood, Thomas M., Smart, J. E. and Chaplin, Adrian B. (2023) Iridium complexes of an ortho-trifluoromethylphenyl substituted PONOP pincer ligand. Dalton Transactions, 52 (4). pp. 1096-1104. doi:10.1039/D2DT03608H ISSN 1477-9226.
2022
Longcake, Alexandra, Lees, Martin R., Senn, Mark S. and Chaplin, Adrian B. (2022) Oxidative addition of CβCl bonds to a Rh(PONOP) pincer complex. Organometallics, 41 (23). pp. 3557-3567. doi:10.1021/acs.organomet.2c00400 ISSN 0276-7333.
Parker, Gemma L., Van Lommel, R., Roig, N., Alonso, M. (Maria) and Chaplin, Adrian B. (2022) Modulation of metal carbonyl stretching frequencies in the second coordination sphere through the internal Stark effect. Chemistry - A European Journal, 28 (69). e202202283. doi:10.1002/chem.202202283 ISSN 1521-3765.
Sinclair, Matthew J. G. and Chaplin, Adrian B. (2022) Heterolytic carbonβiodine bond cleavage by palladium(i) metalloradical. Dalton Transactions, 51 (31). pp. 11617-11619. doi:10.1039/d2dt02152h ISSN 1477-9234.
2021
Hood, Thomas M. and Chaplin, Adrian B. (2021) Synthesis and reactivity of iridium complexes of a macrocyclic PNP pincer ligand. Dalton Transactions, 50 (7). pp. 2472-2482. doi:10.1039/D0DT04303F ISSN 1477-9226.
2020
Leforestier, Baptiste, Gyton, Matthew R. and Chaplin, Adrian B. (2020) Oxidative addition of a mechanically entrapped C(sp)βC(sp) bond to a rhodium(I) pincer complex. Angewandte Chemie International Edition, 59 (52). pp. 23500-23504. doi:10.1002/anie.202009546 ISSN 1433-7851.
Hood, Thomas M. and Chaplin, Adrian B. (2020) Reactions of Rh(PNP) pincer complexes with terminal alkynes : homocoupling through a ring or not at all. Dalton Transactions, 49 (46). pp. 16649-16652. doi:10.1039/D0DT03550E ISSN 1477-9226.
Sinclair, Matthew J. G. and Chaplin, Adrian B. (2020) Oxidative ring expansion of a low-coordinate palladacycle : synthesis of a robust T-shaped alkylpalladium(II) complex. Inorganica Chimica Acta, 513 . 119948. doi:10.1016/j.ica.2020.119948 ISSN 0020-1693.
Storey, Caroline M., Gyton, Matthew R., Andrew, Rhiann E. and Chaplin, Adrian B. (2020) Terminal alkyne coupling reactions through a ring : effect of ring size on rate and regioselectivity. Chemistry - A European Journal, 26 (64). pp. 14715-14723. doi:10.1002/chem.202002962 ISSN 0947-6539.
Kynman, Amy E., Lau, Samantha, Dowd, Sean O., KrΓ€mer, Tobias and Chaplin, Adrian B. (2020) Oxidative addition of biphenylene and chlorobenzene to a Rh(CNC) complex. European Journal of Inorganic Chemistry, 41 . 3899-3906 . doi:10.1002/ejic.202000780 ISSN 1434-1948.
Gyton, Matthew R., Kynman, Amy E., Leforestier, Baptiste, Gallo, Angello, Lewandowski, JΓ³zef R. and Chaplin, Adrian B. (2020) Isolation and structural characterisation of rhodium(III) Ξ·2βfluoroarene complexes : experimental verification of predicted regioselectivity. Dalton Transactions, 49 . pp. 5791-5793. doi:10.1039/D0DT01137A ISSN 1477-9226.
Leforestier, Baptiste, Gyton, Matthew R. and Chaplin, Adrian B. (2020) Synthesis and group 9 complexes of macrocyclic PCP and POCOP pincer ligands. Dalton Transactions, 49 (7). pp. 2087-2101. doi:10.1039/C9DT04835A ISSN 1477-9226.
Storey, Caroline M., Kalpokas, Audrius, Gyton, Matthew R., KrΓ€mer, Tobias and Chaplin, Adrian B. (2020) A shape changing tandem Rh(CNC) catalyst : preparation of bicyclo[4.2.0]octa-1,5,7-trienes from terminal aryl alkynes. Chemical Science, 11 (8). pp. 2051-2057. doi:10.1039/C9SC06153C ISSN 2041-6520.
Hood, Thomas M., Gyton, Matthew R. and Chaplin, Adrian B. (2020) Synthesis and rhodium complexes of macrocyclic PNP and PONOP pincer ligands. Dalton Transactions, 49 (7). pp. 2077-2086. doi:10.1039/C9DT04474D ISSN 1477-9226.
2019
Gyton, Matthew R., Leforestier, Baptiste and Chaplin, Adrian B. (2019) Rhodium(I) pincer complexes of nitrous oxide. Angewandte Chemie International Edition, 58 (43). pp. 15295-15298. doi:10.1002/anie.201908333 ISSN 1433-7851.
Parker, Gemma L., Lau, Samantha, Leforestier, Baptiste and Chaplin, Adrian B. (2019) Probing the donor properties of pincer ligands using rhodium carbonyl fragments : an experimental and computational case study. European Journal of Inorganic Chemistry, 2019 (33). pp. 3791-3798. doi:10.1002/ejic.201900727 ISSN 1434-1948.
Hood, Thomas M., Leforestier, Baptiste, Gyton, Matthew R. and Chaplin, Adrian B. (2019) Synthesis and structural dynamics of five-coordinate Rh(III) and Ir(III) PNP and PONOP pincer complexes. Inorganic Chemistry, 58 (11). pp. 7593-7601. doi:10.1021/acs.inorgchem.9b00957 ISSN 0020-1669.
Emerson-King, Jack, Prokes, Ivan and Chaplin, Adrian B. (2019) Rhodium(III) complexes featuring coordinated CF3 appendages. Chemistry - A European Journal, 25 (25). pp. 6317-6319. doi:10.1002/chem.201901184 ISSN 0947-6539.
Emerson-King, Jack, Prokes, Ivan and Chaplin, Adrian B. (2019) Data for Rhodium(III) complexes featuring coordinated CF3 appendages. [Dataset]
Gyton, Matthew R., Hood, Thomas M. and Chaplin, Adrian B. (2019) A convenient method for the generation of {Rh(PNP)}+ and {Rh(PONOP)}+ fragments : reversible formation of vinylidene derivatives. Dalton Transactions, 9 . 2877. ISSN 1477-9226.
2018
Gyton, Matthew R., Leforestier, Baptiste and Chaplin, Adrian B. (2018) Rhodium(III) and iridium(III) complexes of a NHC-based macrocycle : persistent weak agostic interactions and reactions with dihydrogen. Organometallics, 37 (21). pp. 3963-3971. doi:10.1021/acs.organomet.8b00595 ISSN 0276-7333.
Simpson, Quillon, Sinclair, Matthew J. G., Lupton, David W., Chaplin, Adrian B. and Hooper, Joel F. (2018) Oxidative cross-coupling of boron and antimony nucleo-philes via palladium(I). Organic Letters, 20 (18). pp. 5537-5540. doi:10.1021/acs.orglett.8b01989 ISSN 1523-7060.
Storey, Caroline M., Gyton, Matthew R., Andrew, Rhiann E. and Chaplin, Adrian B. (2018) Terminal alkyne coupling reactions through a ring : mechanistic insights and regiochemical switching. Angewandte Chemie International Edition, 57 (37). pp. 12003-12006. doi:10.1002/anie.201807028 ISSN 1433-7851.
Knighton, Richard C., Emerson-King, Jack, Rourke, Jonathan, Ohlin, AndrΓ© and Chaplin, Adrian B. (2018) Solution, solid-state, and computational analysis of agostic interactions in a coherent set of low-coordinate rhodium(III) and iridium(III) complexes. Chemistry - A European Journal, 24 (19). pp. 4927-4938. doi:10.1002/chem.201705990 ISSN 0947-6539.
Apps, Samantha L., Alflatt, Rhiannon E., Leforestier, Baptiste, Storey, Caroline M. and Chaplin, Adrian B. (2018) Divergent stereoisomers of molybdenum carbonyl complexes of NHC-based pincer ligands. Polyhedron, 143 . pp. 57-61. doi:10.1016/j.poly.2017.08.001 ISSN 0277-5387.
2017
Emerson-King, Jack, Hauser, Simone A. and Chaplin, Adrian B. (2017) CβF bond activation of perfluorinated arenes by a bioxazoline-derived N-heterocyclic carbene. Organic and Biomolecular Chemistry, 15 (4). pp. 787-789. doi:10.1039/C6OB02556K ISSN 1477-0520.
Patchett, Ruth, Knighton, Richard C., Mattock, James D, Vargas, Alfredo and Chaplin, Adrian B. (2017) Potassium binding adjacent to cationic transition metal fragments : unusual heterobimetallic adducts of a calix[4]arene-based thione ligand. Inorganic Chemistry, 56 (22). pp. 14345-14350. doi:10.1021/acs.inorgchem.7b02441 ISSN 0020-1669.
Emerson-King, Jack, Knighton, Richard C., Gyton, Matthew R. and Chaplin, Adrian B. (2017) Rotaxane synthesis exploiting the M(i)/M(iii) redox couple. Dalton Transactions, 46 (35). pp. 11645-11655. doi:10.1039/c7dt02648j ISSN 1477-9226.
Knighton, Richard C. and Chaplin, Adrian B. (2017) Synthesis, structure and binding properties of a series of dissymmetric resorcin[4]arene-based cavitands. Tetrahedron, 73 (31). pp. 4591-4596. doi:10.1016/j.tet.2017.06.023 ISSN 0040-4020 .
GonzΓ‘lez-SebastiΓ‘n, Lucer and Chaplin, Adrian B. (2017) Synthesis and complexes of imidazolinylidene-based CCC pincer ligands. Inorganica Chimica Acta, 460 . pp. 22-28. doi:10.1016/j.ica.2016.08.006 ISSN 0020-1693.
Pike, Sebastian D., Crimmin, Mark R. and Chaplin, Adrian B. (2017) Organometallic chemistry using partially fluorinated benzenes. Chemical Communications, 53 (26). pp. 3615-3633. doi:10.1039/C6CC09575E ISSN 1359-7345.
Hauser, Simone A., Emerson-King, Jack, Habershon, Scott and Chaplin, Adrian B. (2017) UV-light promoted CβH bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex. Chemical Communications, 53 (26). pp. 3634-3636. doi:10.1039/C6CC09807J ISSN 1359-7345.
2016
Patchett, Ruth and Chaplin, Adrian B. (2016) Coordination chemistry of a calix[4]arene-based NHC ligand : dinuclear complexes and comparison to IiPr2Me2. Dalton Transactions, 45 (21). pp. 8945-8955. doi:10.1039/c6dt01001f ISSN 1477-9226.
Andrew, Rhiann, Storey, Caroline M. and Chaplin, Adrian B. (2016) Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles. Dalton Transactions, 45 (21). pp. 8937-8944. doi:10.1039/c6dt01263a ISSN 1477-9226.
Troadec, Thibault, Tan, Sze-yin, Wedge, Christopher, Rourke, Jonathan, Unwin, Patrick R. and Chaplin, Adrian B. (2016) One-electron oxidation of [M(PtBu3)2] (M=Pd, Pt) : isolation of monomeric [Pd(PtBu3)2]+and redox-promoted CβH bond cyclometalation. Angewandte Chemie International Edition, 55 (11). pp. 3754-3757. doi:10.1002/anie.201511467 ISSN 1433-7851.
Andrew, Rhiann, GonzΓ‘lez-SebastiΓ‘n, Lucero and Chaplin, Adrian B. (2016) NHC-based pincer ligands : carbenes with a bite. Dalton Transactions, 45 (4). pp. 1299-1305. doi:10.1039/c5dt04429d ISSN 1477-9226.
2015
Luy, Jan-Niclas, Hauser, Simone A., Chaplin, Adrian B. and Tonner, Ralf (2015) Rhodium(I) and Iridium(I) complexes of the conformationally rigid IBioxMe4Ligand : computational and experimental studies of unusually tilted NHC coordination geometries. Organometallics, 34 (20). pp. 5099-5112. doi:10.1021/acs.organomet.5b00692 ISSN 0276-7333.
Hauser, Simone A., Tonner, Ralf and Chaplin, Adrian B. (2015) Iridium complexes of the conformationally rigid IBioxMe4Ligand : hydride complexes and dehydrogenation of cyclooctene. Organometallics, 34 (17). pp. 4419-4427. doi:10.1021/acs.organomet.5b00658 ISSN 0276-7333.
Troadec, Thibault, Thompson, Amber L. and Chaplin, Adrian B. (2015) Sodium template synthesis of a 54-membered bis(pyridine) macrocycle. Tetrahedron Letters, 56 (31). pp. 4613-4615. doi:10.1016/j.tetlet.2015.05.110 ISSN 0040-4039.
Hauser, Simone A., Prokes, Ivan and Chaplin, Adrian B. (2015) Low-coordinate iridium NHC complexes derived from selective and reversible CβH bond activation of fluoroarenes. Chemical Communications, 51 (21). pp. 4425-4428. doi:10.1039/c5cc00529a ISSN 1359-7345.
Andrew, Rhiann, Ferdani, Dominic W., Ohlin, C. AndrΓ© and Chaplin, Adrian B. (2015) Coordination induced atropisomerism in an NHC-based rhodium macrocycle. Organometallics, 34 (5). pp. 913-917. doi:10.1021/om501292k ISSN 0276-7333.
Andrew, Rhiann and Chaplin, Adrian B. (2015) Synthesis and reactivity of NHC-based rhodium macrocycles. Inorganic Chemistry, 54 (1). pp. 312-322. doi:10.1021/ic5024828 ISSN 0020-1669.
2014
Chaplin, Adrian B. (2014) Rhodium(I) complexes of the conformationally rigid IBioxMe4Ligand : preparation of mono-, bis-, and tris-ligated NHC complexes. Organometallics, Volume 33 (Number 12). pp. 3069-3077. doi:10.1021/om500332n ISSN 0276-7333.
Chaplin, Adrian B. (2014) Rhodium(I) complexes of the conformationally rigid IBioxMe4Ligand : isolation of a stable low-coordinate T-shaped complex. Organometallics, 33 (3). pp. 624-626. doi:10.1021/om401223w ISSN 0276-7333.
Boyt, Stuart M. and Chaplin, Adrian B. (2014) 2,6-Bis[1-(2,4,6-trimethylphenylimino)ethyl]pyridine. Acta Crystallographica Section E Structure Reports Online, Volume 70 (Number 1). Article number o73. doi:10.1107/S1600536813033801 ISSN 1600-5368.
Wheatley, James E., Ohlin, C. AndrΓ© and Chaplin, Adrian B. (2014) Solvent promoted reversible cyclometalation in a tethered NHC iridium complex. Chemical Communications, 50 (6). pp. 685-687. doi:10.1039/c3cc48015a ISSN 1359-7345.
Andrew, Rhiann and Chaplin, Adrian B. (2014) Synthesis, structure and dynamics of NHC-based palladium macrocycles. Dalton Transactions, Volume 43 (Number). pp. 1413-1423. doi:10.1039/c3dt52578c ISSN 1477-9226.
2013
Chaplin, Adrian B. and Weller, Andrew S. (2013) The influence of phosphine cone angle on the synthesis and structures of [Rh(PR3)(BinorβS)]+ complexes that show CβC sigma interactions. Journal of Organometallic Chemistry, Volume 730 . pp. 90-94. doi:10.1016/j.jorganchem.2012.09.013 ISSN 0022-328X.
2012
Pernik, Indrek, Hooper, Joel F., Chaplin, Adrian B., Weller, Andrew S. and Willis, Michael C. (2012) Exploring small bite-angle ligands for the rhodium-catalyzed Intermolecular hydroacylation of Ξ²-S-substituted aldehydes with 1-octene and 1-octyne. ACS Catalysis, Volume 2 (Number 12). pp. 2779-2786. doi:10.1021/cs300541m ISSN 2155-5435.
Chaplin, Adrian B., Hooper, Joel F., Weller, Andrew S. and Willis, Michael C. (2012) Intermolecular hydroacylation : high activity rhodium catalysts containing small-bite-angle diphosphine ligands. Journal of the American Chemical Society, Vol.134 (No.10). pp. 4885-4897. doi:10.1021/ja211649a ISSN 0002-7863.
2011
Pike, Sebastian D., Pawley, R, Chaplin, Adrian B., Thompson, Amber L., Hooper, Joel A., Willis, Michael C. and Weller, Andrew S. (2011) Exploring (Ph2PCH2CH2)2E ligand space (E = O, S, PPh) in RhI alkene complexes as potential hydroacylation catalysts. European Journal of Inorganic Chemistry, Vol.2011 (No.36). pp. 5558-5565. doi:10.1002/ejic.201100958 ISSN 1434-1948.
Chaplin, Adrian B. and Weller, Andrew S. (2011) A rhodium(III) complex of the linear diborazine H3BΒ·NMe2BH2Β·NMe2H : an intermediate in the dehydrocoupling of H3BΒ·NMe2H. Acta Crystallographica. Section C: Crystal Structure Communications, Vol.67 (No.11). m355-m358. doi:10.1107/S0108270111043447 ISSN 0108-2701.
Chaplin, Adrian B., Green, J. C. (Jennifer C.) and Weller, Andrew S. (2011) CβC activation in the solid state in an organometallic Ο-complex. Journal of the American Chemical Society, Vol.133 (No.33). pp. 13162-13168. doi:10.1021/ja2047599 ISSN 0002-7863.
Chaplin, Adrian B. and Weller, Andrew S. (2011) [Rh{NC5H3-2,6-(CH2PtBu2)2}(PCy3)][BArF4] : a latent low-coordinate rhodium(I) PNP pincer compound. Organometallics, Vol.30 (No.16). pp. 4466-4469. doi:10.1021/om2004964 ISSN 0276-7333.
Pontiggia, Ashley J., Chaplin, Adrian B. and Weller, Andrew S. (2011) Cationic iridium complexes of the Xantphos ligand. Flexible coordination modes and the isolation of the hydride insertion product with an alkene. Journal of Organometallic Chemistry, Vol.696 (No.17). pp. 2870-2876. doi:10.1016/j.jorganchem.2011.01.036 ISSN 0022-328X.
Sewell, Laura J., Chaplin, Adrian B. and Weller, Andrew S. (2011) Hydroboration of an alkene by amineβboranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation. Dalton Transactions, Vol.40 (No.29). pp. 7499-7501. doi:10.1039/c1dt10819k ISSN 1477-9226.
Johnson, Heather C., Robertson, Alasdair P. M., Chaplin, Adrian B., Sewell, Laura J., Thompson, Amber L., Haddow, Mairi F., Manners, Ian and Weller, Andrew S. (2011) Catching the first oligomerization event in the catalytic formation of polyaminoboranes : H3BΒ·NMeHBH2Β·NMeH2 bound to iridium. Journal of the American Chemical Society, Vol.133 (No.29). pp. 11076-11079. doi:10.1021/ja2040738 ISSN 0002-7863.
Dallanegra, Romaeo, Pilgrim, Ben S., Chaplin, Adrian B., Donohoe, Timothy J. and Weller, Andrew S. (2011) Dehydrogenation of cyclic thioethers bound to a [Rh(diphosphine)]+ fragment. Dalton Transactions, Vol.40 (No.25). pp. 6626-6628. doi:10.1039/c1dt10503e ISSN 1477-9226.
Chaplin, Adrian B. and Dyson, Paul J. (2011) Influence of arene dissociation and phosphine coordination on the catalytic activity of [RuCl(ΞΊ2-triphos)(p-cymene)]PF6. Journal of Organometallic Chemistry, Vol.696 (No.13). pp. 2485-2490. doi:10.1016/j.jorganchem.2011.02.022 ISSN 0022-328X.
GonzΓ‘lez-RodrΓguez, Carlos, Pawley, Rebekah J., Chaplin, Adrian B., Thompson, Amber L., Weller, Andrew S. and Willis, Michael C. (2011) Rhodium-catalyzed branched-selective alkyne hydroacylation : a ligand-controlled regioselectivity switch. Angewandte Chemie International Edition, Vol.50 (No.22). pp. 5134-5138. doi:10.1002/anie.201100956 ISSN 1433-7851.
Dallanegra, Romaeo, Robertson, Alasdair P. M., Chaplin, Adrian B., Manners, Ian and Weller, Andrew S. (2011) Tuning the [L2Rhβ―H3BΒ·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes. Chemical Communications, Vol.47 (No.13). pp. 3763-3765. doi:10.1039/c0cc05460g ISSN 1359-7345.
Woolf, Anthony, Chaplin, Adrian B., McGrady, John E., Alibadi, Muhsen A. M., Rees, Nicholas H., Draper, Sylvia, Murphy, F. (Frances) and Weller, Andrew S. (2011) {Rh(PiBu3)2}+ fragments ligated to arenes : from benzene to polyaromatic hydrocarbons, part I - an experimental approach. European Journal of Inorganic Chemistry, Vol.2011 (No.10). pp. 1614-1625. doi:10.1002/ejic.201001263 ISSN 1434-1948.
Woolf, Anthony, Alibadi, Muhsen A. M., Chaplin, Adrian B., McGrady, J. E. (John E.) and Weller, Andrew S. (2011) {Rh(PiBu3)2}+ fragments ligated to arenes : from benzene to polyaromatic hydrocarbons, part II - computational analysis of pathways for haptotropic migration. European Journal of Inorganic Chemistry, Vol.2011 (No.10). pp. 1626-1634. doi:10.1002/ejic.201001264 ISSN 1434-1948.
Stevens, Charlotte J., Dallanegra, Romaeo, Chaplin, Adrian B., Weller, Andrew S., Macgregor, Stuart A., Ward, B. (Bryan), McKay, D. (David), Alcaraz, Gilles and Sabo-Etienne, Sylviane (2011) [Ir(PCy(3))(2)(H)(2)(H(2)B-NMe(2))](+) as a latent source of aminoborane : probing the role of metal in the dehydrocoupling of H(3)B center dot NMe(2)H and retrodimerisation of [H(2)BNMe(2)](2). Chemistry: A European Journal, Vol.17 (No.10). pp. 3011-3020. doi:10.1002/chem.201002517 ISSN 0947-6539.
2010
Alcaraz, Gilles, Chaplin, Adrian B., Stevens, Charlotte J., Clot, Eric, Vendier, Laure, Weller, Andrew S. and Sabo-Etienne, Sylviane (2010) Ruthenium, rhodium, and iridium bis(Ο-BβH) diisopropylaminoborane complexes. Organometallics, Vol.29 (No.21). pp. 5591-5595. doi:10.1021/om1004995 ISSN 0276-7333.
Chaplin, Adrian B. and Weller, Andrew S. (2010) [B(3,5-C6H3Cl2)4]- as a useful anion for organometallic chemistry. European Journal of Inorganic Chemistry, Vol.2010 (No.32). pp. 5124-5128. doi:10.1002/ejic.201000686 ISSN 1434-1948.
Sparkes, Hazel A., Chaplin, Adrian B., Weller, Andrew S. and Howard, J. A. K. (2010) Bond catastrophes in rhodium complexes : experimental charge-density studies of [Rh(C7H8)(PtBu3)Cl] and [Rh(C7H8)(PCy3)Cl]. Acta Crystallographica. Section B: Structural Science, Vol.66 (No.5). pp. 503-514. doi:10.1107/S0108768110031496 ISSN 0108-7681.
Sewell, Laura J., Chaplin, Adrian B., Abdallah, Joseph A. B. and Weller, Andrew S. (2010) Reversible CβH activation of a PtBuiBu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation. Dalton Transactions, Vol.39 (No.32). pp. 7437-7439. doi:10.1039/c0dt00449a ISSN 1477-9226.
Townsend, Nell S., Chaplin, Adrian B., Naser, M. Abu, Thompson, Amber L., Rees, Nicholas H., Macgregor, Stuart A. and Weller, Andrew S. (2010) Reactivity of the latent 12-electron fragment [Rh(PiBu3)2]+ with aryl bromides : aryl-Br and phosphine ligand C-H activation. Chemistry: A European Journal, Vol.16 (No.28). pp. 8376-8389. doi:10.1002/chem.201000554 ISSN 0947-6539.
Chaplin, Adrian B., Tonner, Ralf and Weller, Andrew S. (2010) Isolation of a low-coordinate rhodium phosphine complex formed by CβC bond activation of biphenylene. Organometallics, Vol.29 (No.12). pp. 2710-2714. doi:10.1021/om100149w ISSN 0276-7333.
Chaplin, Adrian B. and Weller, Andrew S. (2010) CβC bond activation of a cyclopropyl phosphine : isolation and reactivity of a tetrameric rhodacyclobutane. Organometallics, Vol.29 (No.10). pp. 2332-2342. doi:10.1021/om100105p ISSN 0276-7333.
Dallanegra, Romaeo, Chaplin, Adrian B., Tsim, Jennifer and Weller, Andrew S. (2010) Amino-borane oligomers bound to a Rh(i) metal fragment. Chemical Communications, Vol.46 (No.18). pp. 3092-3094. doi:10.1039/c003055d ISSN 1359-7345.
Pawley, Rebekah J., Moxham, Gemma L., Dallanegra, Romaeo, Chaplin, Adrian B., Brayshaw, Simon K., Weller, Andrew S. and Willis, Michael C. (2010) Controlling selectivity in intermolecular alkene or aldehyde hydroacylation reactions catalyzed by {Rh(L2)}+ fragments. Organometallics, Vol.29 (No.7). pp. 1717-1728. doi:10.1021/om9011104 ISSN 0276-7333.
Moret, SΓ©verine, Dallanegra, Romaeo, Chaplin, Adrian B., Douglas, Thomas M., Hiney, Rachel M. and Weller, Andrew S. (2010) Alkyl dehydrogenation in iridium tri-cyclopentyl phosphines. Inorganica Chimica Acta, Vol.363 (No.3). pp. 574-580. doi:10.1016/j.ica.2009.03.004 ISSN 0020-1693.
Chaplin, Adrian B. and Weller, Andrew S. (2010) Amineβ and dimeric aminoβborane complexes of the {Rh(PiPr3)2}+ fragment and their relevance to the transition-metal-mediated dehydrocoupling of amineβboranes. Inorganic Chemistry, Vol.49 (No.3). pp. 1111-1121. doi:10.1021/ic9020542 ISSN 0020-1669.
Hiney, Rachel M., Chaplin, Adrian B., Harmer, Jeffrey, Green, Jennifer C. and Weller, Andrew S. (2010) Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count : [Rh6(PCy3)6H12]+ and [Rh6(PCy3)6H14]+. Dalton Transactions, Vol.39 (No.7). pp. 1726-1733. doi:10.1039/b919209c ISSN 1477-9226.
2009
Douglas, Thomas M., Chaplin, Adrian B., Weller, Andrew S., Yang, Xinzheng and Hall, Michael B. (2009) Monomeric and oligomeric amineβborane Ο-complexes of rhodium. Intermediates in the catalytic dehydrogenation of amineβboranes. Journal of the American Chemical Society, Vol.131 (No.42). pp. 15440-15456. doi:10.1021/ja906070r ISSN 0002-7863.
Dallanegra, Romaeo, Chaplin, Adrian B. and Weller, Andrew S. (2009) Bis(Ο-amine-borane) complexes : an unusual binding mode at a transition-metal center. Angewandte Chemie International Edition, Vol.48 (No.37). pp. 6875-6878. doi:10.1002/anie.200903121 ISSN 1433-7851.
Tang, Christina Y., Smith, W. (William), Vidovic, Dragoslav, Thompson, Amber L., Chaplin, Adrian B. and Aldridge, S. (Simon) (2009) Sterically encumbered iridium bis(N-heterocyclic carbene) systems : multiple CβH activation processes and isomeric normal/abnormal carbene complexes. Organometallics, Vol.28 (No.10). pp. 3059-3066. doi:10.1021/om9000082 ISSN 0276-7333.
Chaplin, Adrian B., Poblador-Bahamonde, Amalia I., Sparkes, Hazel A., Howard, J. A. K., Macgregor, Stuart A. and Weller, Andrew S. (2009) Alkyl dehydrogenation in a Rh(i) complex via an isolated agostic intermediate. Chemical Communications (No.2). pp. 244-246. doi:10.1039/b816739g ISSN 1359-7345.
Chaplin, Adrian B. and Weller, Andrew S. (2009) B-H activation at a rhodium(I) center : isolation of a bimetallic complex relevant to the transition-metal-catalyzed dehydrocoupling of amine-boranes. Angewandte Chemie International Edition, Vol.49 (No.3). pp. 581-584. doi:10.1002/anie.200905185 ISSN 1433-7851.
2008
Douglas, Thomas M., Chaplin, Adrian B. and Weller, Andrew S. (2008) Amine-borane Ο-complexes of rhodium. Relevance to the catalytic dehydrogenation of amine-boranes. Journal of the American Chemical Society, Vol.130 (No.44). pp. 14432-14433. doi:10.1021/ja806582n ISSN 0002-7863.
Douglas, Thomas M., Chaplin, Adrian B. and Weller, Andrew S. (2008) Dihydrogen loss from a 14-electron rhodium(III) bis-phosphine dihydride to give a rhodium(I) complex that undergoes oxidative addition with aryl chlorides. Organometallics, Vol.27 (No.13). pp. 2918-2921. doi:10.1021/om800373d ISSN 0276-7333.
Chaplin, Adrian B., BΓ©ni, ZoltΓ‘n, Hartinger, Christian G., Hamidane, Hisham Ben, Phillips, Andrew D., Scopelliti, Rosario and Dyson, Paul J. (2008) Linked metal-cluster systems : isolation and characterisation of {anti-[(p-cymene)RuCl]-ΞΌ-[ΞΊ 2-P,Pβ²;ΞΊ 1-Pβ²β²-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2. Journal of Cluster Science, Vol.19 (No.1). pp. 295-309. doi:10.1007/s10876-007-0175-0 ISSN 1040-7278.
Chaplin, Adrian B. and Dyson, Paul J. (2008) Reactivity and catalytic activity of a robust ruthenium(II)βtriphos complex. Inorganic Chemistry, Vol.47 (No.1). pp. 381-390. doi:10.1021/ic701773a ISSN 0020-1669.
Chaplin, Adrian B. (2008) Catalytic activity of bis-phosphine ruthenium(II)-arene compounds. Chimia, Vol.62 (No.4). pp. 217-220. doi:10.2533/chimia.2008.217 ISSN 0009-4293.
This list was generated on Thu Mar 28 18:07:06 2024 GMT.