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Copper mediated reversible deactivation radical polymerization in aqueous media
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Jones, Glen R., Anastasaki, Athina, Whitfield, Richard, Engelis, Nikolaos, Liarou, Evelina and Haddleton, David M. (2018) Copper mediated reversible deactivation radical polymerization in aqueous media. Angewandte Chemie , 130 (33). pp. 10628-10643. doi:10.1002/ange.201802091 ISSN 0044-8249.
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Official URL: http://dx.doi.org/10.1002/ange.201802091
Abstract
Key advances within the past 10 years have transformed copper mediated radical polymerization from a technique which was not very tolerant to protic media into a range of closely related processes capable of control over the polymerization of a wide range of monomers in pure water at ppm catalyst loadings; yielding water soluble macromolecules of desired molecular weight, architecture and chemical functionality, with applications ranging from drug delivery to oil field recovery. In this review we highlight and critically evaluate the synthetic methods that have been developed to control radical polymerization in water using copper complexes, identify future areas of interest and challenges still to be overcome.
| Item Type: | Journal Article | |||||||||||||||
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| Subjects: | Q Science > QD Chemistry | |||||||||||||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | |||||||||||||||
| Library of Congress Subject Headings (LCSH): | Polymerization, Monomers, Macromolecules | |||||||||||||||
| Journal or Publication Title: | Angewandte Chemie | |||||||||||||||
| Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | |||||||||||||||
| ISSN: | 0044-8249 | |||||||||||||||
| Official Date: | 13 August 2018 | |||||||||||||||
| Dates: |
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| Volume: | 130 | |||||||||||||||
| Number: | 33 | |||||||||||||||
| Page Range: | pp. 10628-10643 | |||||||||||||||
| DOI: | 10.1002/ange.201802091 | |||||||||||||||
| Status: | Peer Reviewed | |||||||||||||||
| Publication Status: | Published | |||||||||||||||
| Access rights to Published version: | Restricted or Subscription Access | |||||||||||||||
| Date of first compliant deposit: | 4 April 2018 | |||||||||||||||
| Date of first compliant Open Access: | 30 March 2019 | |||||||||||||||
| RIOXX Funder/Project Grant: |
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