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Data for An expanded MIL-53-type coordination polymer with a reactive pendant ligand
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Kunicki, Hannah, Chamberlain, Thomas W., Clarkson, Guy J., Kashtiban, Reza J., Hooper, Joseph E., Dawson, Daniel M., Ashbrook, Sharon E. and Walton, Richard I. (2018) Data for An expanded MIL-53-type coordination polymer with a reactive pendant ligand. [Dataset]
Archive (ZIP) (Thermogravimetric analysis and Measured powder XRD)
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Plain Text (Description of data fields)
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Official URL: http://wrap.warwick.ac.uk/103572
Abstract
A coordination polymer with a structure isoreticular to MIL-53, but containing a divalent metal cation (Co2+ or Mg2+) and a coordinating 4-styrylpyridine-N-oxide ligand, crystallises under solvothermal conditions; the pendant ligand can be brominated, with evidence from powder X-ray diffraction, element mapping and 81Br solid-state NMR for this post-synthesis modification.
Item Type: | Dataset | ||||||||||||||||||||||||
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Subjects: | Q Science > QD Chemistry | ||||||||||||||||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||||||||||||||||||
Type of Data: | Experimental data supporting publication | ||||||||||||||||||||||||
Library of Congress Subject Headings (LCSH): | Coordination polymers, Organometallic compounds, Ligands | ||||||||||||||||||||||||
Publisher: | University of Warwick, Department of Chemistry | ||||||||||||||||||||||||
Official Date: | 3 July 2018 | ||||||||||||||||||||||||
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Status: | Not Peer Reviewed | ||||||||||||||||||||||||
Publication Status: | Published | ||||||||||||||||||||||||
Media of Output (format): | .txt | ||||||||||||||||||||||||
Access rights to Published version: | Open Access (Creative Commons) | ||||||||||||||||||||||||
Copyright Holders: | University of Warwick | ||||||||||||||||||||||||
Description: | Crystal structure are available from the CCDC using the information provided in the paper. Thermogravimetric analysis (TGA-DSC in Figure 3a) is provded in an ascii file in x,y1,y2 format: temperature, percentage mass, heat flow Measured powder XRD (Figure 4a) is provided in acsii files in x,y format: angle, intensity. |
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