The Library
Enantioselective synthesis of aziridines using asymmetric transfer hydrogenation as a precursor for chiral derivatives used as bonding agent for rocket solid propellants
Tools
UNSPECIFIED (2002) Enantioselective synthesis of aziridines using asymmetric transfer hydrogenation as a precursor for chiral derivatives used as bonding agent for rocket solid propellants. QUIMICA NOVA, 25 (6A). pp. 921-925. ISSN 0100-4042.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Abstract
A rapid, expedient and enantioselective method for the synthesis of beta-hydroxy amines and monosubstituted aziridines in up to 99% e.e., via asymmetric transfer hydrogenation of a-amino ketones and cyclisation through treatment with tosyl chloride and base, is described. (1R,2R)-N-(para-toluenesulfonyl)-1,2-ethylenediamine with formic acid has been utilised as a ligand for the Ruthenium (II) catalysed enantioselective transfer hydrogenation of the ketones. The chiral 2-methyl aziridine, which is a potentially more efficient bonding agent for Rocket Solid Propellant has been successfully achieved.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | QUIMICA NOVA | ||||
Publisher: | SOC BRASILEIRA QUIMICA | ||||
ISSN: | 0100-4042 | ||||
Official Date: | November 2002 | ||||
Dates: |
|
||||
Volume: | 25 | ||||
Number: | 6A | ||||
Number of Pages: | 5 | ||||
Page Range: | pp. 921-925 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |