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2-D soft ferromagnet based on [W-V(CN)(8)](3-) and Cu-II with a T-c of 34 K
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UNSPECIFIED (2002) 2-D soft ferromagnet based on [W-V(CN)(8)](3-) and Cu-II with a T-c of 34 K. CHEMICAL COMMUNICATIONS (10). pp. 1138-1139. doi:10.1039/b202810g ISSN 1359-7345.
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Official URL: http://dx.doi.org/10.1039/b202810g
Abstract
Self-assembly of [Cu(tetren)](2+) (tetren = tetraethylenepentamine) and [W(CN)(8)](3-) in acidic aqueous solution yields the double-layered square grid cyanide-bridged polymer of {(tetrenH(5))(0.8)Cu-4(II)[W-v(CN)(8)](4).7.2H(2)O}(n) with Cu(II) centres of square pyramidal geometry coordinatively saturated solely by CN bridges supplied by five [W(CN)(8)](3-) ions; it exhibits soft ferromagnetic behaviour with an ordering temperature T-c of 34 K.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | CHEMICAL COMMUNICATIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 1359-7345 | ||||
Official Date: | 2002 | ||||
Dates: |
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Number: | 10 | ||||
Number of Pages: | 2 | ||||
Page Range: | pp. 1138-1139 | ||||
DOI: | 10.1039/b202810g | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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