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Synthesis of 2,5-dihydrofurans via alkylidene carbene insertion reactions
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UNSPECIFIED (2002) Synthesis of 2,5-dihydrofurans via alkylidene carbene insertion reactions. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 (7). pp. 965-981. doi:10.1039/b111097g ISSN 1472-7781.
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Official URL: http://dx.doi.org/10.1039/b111097g
Abstract
The insertion reaction of alkylidene carbenes is demonstrated to be an effective method for the synthesis of 2,5-dihydrofuran ring systems. The best results have been obtained on substrates containing electron-withdrawing substituents, which appear less prone to the competing rearrangement reaction. This insight has led to the development of a new method for the synthesis of the core structure of the squalestatin-zaragozic acid natural products.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 1472-7781 | ||||
Official Date: | 2002 | ||||
Dates: |
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Number: | 7 | ||||
Number of Pages: | 17 | ||||
Page Range: | pp. 965-981 | ||||
DOI: | 10.1039/b111097g | ||||
Publication Status: | Published |
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