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Problems and solutions for alkene polymerisation catalysts incorporating Schiff-bases; migratory insertion and radical mechanisms of catalyst deactivation
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UNSPECIFIED (2002) Problems and solutions for alkene polymerisation catalysts incorporating Schiff-bases; migratory insertion and radical mechanisms of catalyst deactivation. CHEMICAL COMMUNICATIONS (4). pp. 352-353. ISSN 1359-7345.
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Abstract
Steric blocking of an intramolecular 1,2-migratory insertion reaction of a zirconium salicylaldiminato complex leads to a long-lived catalyst for ethene polymerisation, but promotes a new radical catalyst decomposition mechanism in certain instances; kinetic and thermodynamic parameters for both pathways have been established.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | CHEMICAL COMMUNICATIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 1359-7345 | ||||
Official Date: | 2002 | ||||
Dates: |
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Number: | 4 | ||||
Number of Pages: | 2 | ||||
Page Range: | pp. 352-353 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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